947536-19-8

Upstream product

• 17590-58-8 2-benzylidene-1,3-dithiane 

Downstream Products

• 1433278-87-5 S-butyl 2-((1,3-dithian-2-ylidene)(phenyl)methyl)octanethioate 
• 1433278-71-7 3-(1,3-dithian-2-ylidene)-N-methyl-2,3-diphenyl-N-tosylpropanamide 
• 1433278-90-0 S-butyl 3-(1,3-dithian-2-ylidene)-3-phenyl-2-(4-methylphenyl)propanethioate 
• 1433278-81-9 1-butyl-2-(4-cyanophenyl)-4-(4-methylphenyl)-3-phenyl-5-(2-thienyl)pyrrole 
• 1433278-80-8 2-(4-cyanophenyl)-4-(4-methylphenyl)-3-phenyl-5-(2-thienyl)furan 
• 1433278-86-4 C₂₅H₂₆O₂S₃ 
• 1433278-85-3 C₂₄H₂₂OS₃ 
• 1433278-95-5 C₂₄H₃₀O₂S₃ 
• 103-82-2 phenylacetic acid 
• 36998-40-0 2,2-diphenylmethylene-1,3-dithiane 
• 1058164-29-6 C₂₀H₂₂S₂ 
• 1058164-23-0 2-[phenyl(4-tolyl)methylene]-1,3-dithiane 
• 1058164-24-1 C₁₇H₁₅ClS₂ 
• 1058164-26-3 2-[(4-methoxyphenyl)phenylmethylene]-1,3-dithiane 

Relevant academic research and scientific papers

Copper-catalyzed extended pummerer reactions of ketene dithioacetal monoxides with alkynyl sulfides and ynamides with an accompanying oxygen rearrangement

The first examples of metal-catalyzed extended Pummerer reactions through the activation of sulfoxides are described. The copper-catalyzed reactions of ketene dithioacetal monoxides with alkynyl sulfides and ynamides provided a wide variety of γ,γ-disulfanyl-β,γ-unsaturated carbonyl compounds with an accompanying oxygen rearrangement. The products can be easily converted into 1,4-dicarbonyl compounds and substituted heteroaromatics. DFT calculations and mechanistic experiments revealed a new interesting stepwise addition/oxygen rearrangement mechanism. Beyond Pummerer: The first examples of copper-catalyzed extended Pummerer reactions of ketene dithioacetal monoxides with alkynyl sulfides and ynamides provided a wide variety of γ,γ-disulfanyl-β,γ-unsaturated carbonyl compounds with an accompanying oxygen rearrangement (see scheme). The products can be easily converted into 1,4-dicarbonyl compounds and substituted heteroaromatics. DFT calculations and mechanistic experiments revealed a new interesting stepwise addition/oxygen-rearrangement mechanism.