947546-75-0

Upstream product

• 935223-82-8 2-bromo-4-methyl-1-[2-(trimethylsilyl)ethynyl]benzene 
• 583-68-6 2-bromo-p-toluidine 
• 71838-16-9 3-bromo-4-iodotoluene 

Downstream Products

• 1150112-13-2 1-(2-bromo-4-methylphenyl)-2-(4-methylphenyl)ethyne 
• 1150112-14-3 1-(2-bromo-4-methylphenyl)-2-(4-methoxyphenyl)ethyne 
• 1150112-15-4 1-(2-bromo-4-methylphenyl)-2-(4-methoxycarbonylphenyl)ethyne 
• 1150112-12-1 ethyl 3-(2-bromo-4-methylphenyl)propiolate 
• 103286-27-7 2-bromo-4-methylacetophenone 
• 947546-26-1 4-methyl-2-(prop-1-ynyl)-1-((2-(prop-1-ynyl)-4-(trifluoromethyl)phenyl)ethynyl)benzene 
• 947546-77-2 C₁₆H₉I₂F₃ 

Relevant academic research and scientific papers

Auto-Tandem Palladium Catalysis: From Isoxazole to 2-Azafluorenone

An auto-tandem palladium catalysis from halogen-substituted isoxazoles and Michael acceptors is described. It involves two mechanistically distinct palladium-catalyzed reactions, a Heck reaction and a rearrangement, leading to 2-azafluorenones. It is the

One-Pot Copper-Catalyzed Three-Component Reaction of Sulfonyl Azides, Alkynes, and Allylamines to Access 2,3-Dihydro-1 H-imi-dazo[1,2-a]indoles

A copper-catalyzed multicomponent reaction of sulfonyl azides, alkynes, and allylamines affording 2,3-dihydro-1 H-imidazo-[1,2-a]indoles in moderate yields is reported. Four C-N bonds are constructed- by way of azide-alkyne cycloaddition (CuAAC) and double Ullmann-type coupling reactions in a one-pot process.

An extremely simple dibenzopentalene synthesis from 2-bromo-1- ethynylbenzenes using nickel(O) complexes: Construction of its derivatives with various functionalities

An extremely simple dibenzopentalene synthesis from readily available 2-bromo-1-ethynylbenzenes using a nickel(O) complex is described. Although the yields are moderate, the formation of three C-C bonds in a single process and the high availability of the

PtCl2-catalyzed hydrative cyclization of trialkyne functionalities to form bicyclic spiro ketones

(Chemical Equation Presented) Triple rounds: A regioselective hydrative cyclization of triynes has been developed to give bicyclic β-hydroxy spiro ketones, which undergo subsequent dehydration to give the β,γ- unsaturated ketones (see scheme). Model reactions suggest that this platinum catalysis includes two selective hydrations, an alkyne insertion, and an aldol condensation.