94757-29-6Relevant academic research and scientific papers
α-Umpolung of Ketones and Aldehydes via the Corresponding Silyl Enol Ether Cation Radicals
Schmittel, Michael,Levis, Michael
, p. 1939 - 1940 (1994)
The α-Umpolung of ketones and aldehydes via their silyl enol ether cation radicals has been developed and tested for the use of different nucleophiles.
α-Umpolung of Ketones via Enol Cation Radicals. Mechanistic and Synthetic Aspects
Schmittel, Michael,Levis, Michael
, p. 1935 - 1938 (2007/10/02)
The novel α-Umpolung of ketones via intermediate enol cation radicals has been explored mechanistically and tested for different nucleophiles that are compatible to the oxidative conditions.The rate of the reaction was determined indicating that enolizati
