94768-53-3Relevant academic research and scientific papers
ALKOXIDE-ACCELERATED SIGMATROPIC SHIFTS OF BICYCLONON-6-EN-2-OLS. SUBSTITUENT EFFECTS AND TANDEM - SIGMATROPIC REARRANGEMENTS
Uyehara, Tadao,Ohmori, Kazuhiro,Kabasawa, Yasuhiro,Kato, Tadahiro
, p. 1879 - 1882 (1984)
Bicyclonon-6-en-2-ols are shown to undergo sigmatropic shifts under the influence of KH and 18-crown-6.A series of the 2-endo-vinyl alcohols were transformed into the ring-expanded ketones, bicycloundec-8-en-4-ones, via the tandem - sigmatropic rearrangements.
