94771-83-2Relevant articles and documents
1,3,5-triaza-7-phosphaadamantane (PTA): A practical and versatile nucleophilic phosphine organocatalyst
Tang, Xiaofang,Zhang, Bo,He, Zhengrong,Gao, Ruili,He, Zhengjie
, p. 2007 - 2017 (2008/09/18)
In this paper, the air-stable and readily available 1,3,5-triaza-7- phosphaadmantane (PTA) is reported as a practical and versatile nucleophilic phosphine organocatalyst. Under the mediation of 15-30 mol% of PTA, various electrophiles like aldehydes and i
Synthesis of unsaturated β-amino acid derivatives from carbamates of the Baylis-Hillman products
Ciclosi, Marco,Fava, Cristiana,Galeazzi, Roberta,Orena, Mario,Sepulveda-Arques, José
, p. 2199 - 2202 (2007/10/03)
By treatment with a catalytic amount of DBU in DCM, N-p-toluenesulphonyl carbamates 6a-c, prepared starting from the corresponding Baylis-Hillman adducts, gave (E)-2-(p-toluenesulphonylaminomethyl)propenoates 3a-c, exclusively. On the contrary, changing D
Friedel-Crafts reaction of the Baylis-Hillman adducts of N-tosylimine derivatives
Lee, Hong Jung,Seong, Mi Ra,Kim, Jae Nyoung
, p. 6223 - 6226 (2007/10/03)
Friedel-Crafts reaction of aromatic compounds with the Baylis-Hillman adducts of N-tosylimine derivatives in the presence of sulfuric acid provided a stereoselective methodology for the preparation of 2-benzylsubstituted olefins in moderate yields.