947740-50-3Relevant academic research and scientific papers
Unexpected reactivity of graphene oxide with DBU and DMF
Ramírez-Jiménez, Rafael,Franco, Mario,Rodrigo, Eduardo,Sainz, Raquel,Ferritto, Rafael,Lamsabhi, Al Mokhtar,Ace?a, José Luis,Cid, M. Belén
, p. 12637 - 12646 (2018/07/13)
An unusual reaction between GO, DBU and DMF, that typically uses base and solvent, has been thoroughly analyzed providing valuable basic knowledge about the reactivity of GO, which is essential to control functionalization and therefore the properties of
An Asymmetric Vinylogous Michael Cascade of Silyl Glyoximide, Vinyl Grignard, and Nitroalkenes via Long Range Stereoinduction
Boyce, Gregory R.,Johnson, Jeffrey S.
, p. 1712 - 1717 (2016/03/01)
A diastereoselective auxiliary-mediated vinylation/[1,2]-Brook rearrangement/vinylogous Michael cascade of silyl glyoximide, vinylmagnesium bromide, and nitroalkenes is described. The reaction occurs with complete regio- and diastereocontrol in good yield. The diastereoselectivity is induced by a rare instance of 1,7-chirality transfer that is hypothesized to arise from a trans-multihetero-decalin transition state. (Chemical Equation).
