94780-63-9Relevant academic research and scientific papers
SYNTHESIS OF AN OSMIUM(II) COMPLEX WITH THE PIPh LIGAND AND A POSSIBLE TERMINAL PHENYLPHOSPHINIDENE COMPLEX INTERMEDIATE FROM IODIDE ABSTRACTION
Bohle, D. S.,Roper, W. R.
, p. C4 - C6 (2007/10/02)
Addition of I2 to Os(PHPh)Cl(CO)2(PPh3)2 gives + and deprotonation of this cation affords Os(PIPh)Cl(CO)2(PPh3)2.The iodophenylphosphido complex reacts with AgSbF6 in THF/MeOH to give (CO)2(PPh3)2>SbF6 suggesting the intermediacy of a phenylphosphinidene complex +.
