94799-97-0Relevant articles and documents
Use of BF4 to prepare thiolate complexes of iron and ruthenium
Treichel, P. M.,Rublein, E. K.
, p. 71 - 77 (1992)
The complexes BF4 (L = PPh2Me, PPhMe2 P(OMe)3), 3SMe>BF4, and BF4 were prepared by reactions of BF4 and the appropriate neutral M(CO)5-n(L)n precursor.Several other analogous reactions were unsu
Formaldehyde Complexes
Berke, Heinz,Birk, Reiner,Huttner, Gottfried,Zsolnai, Laszlo
, p. 1380 - 1388 (2007/10/02)
The synthesis of formaldehyde complexes (OC)2L2FeCH2O (L = P(OEt)3 (2b), L = P(OiPr)3 (2c)) and CpRe(CO)2CH2O (3) is reported.A (OC)22FeCH2O compound (2a) reacts with CO, PPh3 and C2H4 substituting the CH2O ligand.CH3I and H2 also cause elimination of formaldehyde with oxidative addition to the Fe(CO)22 fragment.HI adds to 2c to give a iodomethyl complex 5, which has been characterized by an X-ray structure determination. - Keywords: Formaldehyde Complexes, Substitution Reactions, Iodomethyliron Complexes