948018-43-7Relevant articles and documents
New P,N-ferrocenyl ligands for the asymmetric Ir-catalyzed hydrogenation of imines
Cheemala, Murthy N.,Knochel, Paul
, p. 3089 - 3092 (2008/02/09)
The Ir-catalyzed enantioselective hydrogenation of various N-3,5-dimethyl-4-methoxy)phenylimines was performed under mild conditions in the presence of new P,N-ferrocenyl iridium complexes leading to (R)-N-(3,5-dimethyl-4-methoxy)phenylamines in high yields and enantioselectivities (up to 99%). These chiral aryl amines can be readily deprotected using Ce(NH4)2(NO3)6.