94806-38-9Relevant academic research and scientific papers
ASYMMETRIC METHALLYLBORATION OF PROCHIRAL ALDEHYDES WITH METHALLYLDIISO-PINOCAMPHEYLBORANE. SYNTHESIS OF 2-METHYL-1-ALKEN-1-OLS IN 90percent ENAN-TIOMERIC PURITIES
Brown, Herbert C.,Jadhav, Prabhakar K.,Perumal, P. Thirumalai
, p. 5111 - 5114 (1984)
Methallyldiisopinocampheylborane, on condensation with aldehydes, provides 2-methyl-1-alken-4-ols in 90percent enantiomeric purities.
Stereoselektive Synthese von Alkoholen, VII. Optisch aktive Homoallylalkohole durch Addition chiraler Boronsaeureester an Aldehyde
Hoffmann, Reinhard W.,Herold, Thomas
, p. 375 - 383 (2007/10/02)
Addition of the chiral boronates 1 and 4 to aldehydes led to homoallyl alcohols 2 and 5 of uniform absolute configuration.On addition to saturated aldehydes an asymmetric induction of around 70percent e. e. could be achieved.
