94833-78-0Relevant academic research and scientific papers
Rearrangement Studies on Cycloalkylidene Ring Systems: Differences Between the Reactions of Cycloalkanone Oximes and Cycloalkylidenemalononitriles with Arylmethylidene(cyano)thioacetamides
Elgemeie, Galal E. H.,Alnaimi, Ibrahim S.,Gawad, Mona A.
, p. 424 - 433 (2007/10/02)
A novel synthesis of condensed pyridine-2(1H)-thiones utilizing cycloalkanone oximes and arylmethylidene(cyano)thioacetamides as starting components is described.
CYCLIZATION OF NITRILES. X. ENAMINO NITRILES OF THE 1,3-DITHIA-4-CYCLOHEXENE SERIES AND THEIR RECYCLIZATION TO DERIVATIVES OF PYRIDINE AND THIAZOLE
Sharanin, Yu. K.,Shestopalov, A. M.,Promonenkov, V. K.,Rodinovskaya, L. A.
, p. 1402 - 1415 (2007/10/02)
The recyclization of 4-amino-6-aryl-5-cyano-2-cyclopentane(cyclohexane)spiro-1,3-dithia-4-cyclohexenes, obtained from gem-dithiols and arylidenemalononitriles, leads to the formation of 4-aryl-5,6-polymethylene-3-cyano-2-(1H)-pyridinethiones.The latter are used in the synthesis of various 3-aminothienopyridines, 4-aryl-3-amino-5,6,7,8-tetrahydrothienoquinolines, and other heterocyclic compounds condensed with quinoline. 1-Cyano-1-(4-aryl-2-thiazolyl)-2-arylethylenes were obtained by the reaction of the 1,3-dithia-4-cyclohexenes with phenacyl bromides.
