949028-45-9Relevant academic research and scientific papers
Direct and stereospecific synthesis of allenes via reduction of propargylic alcohols with Cp2Zr(H)Cl
Pu, Xiaotao,Ready, Joseph M.
supporting information; experimental part, p. 10874 - 10875 (2009/02/05)
Allenes can be synthesized via the direct SN2′ addition of hydride to propargylic alcohols. Previous examples of this approach, however, have involved harsh reaction conditions and have suffered from incomplete transfer of central chirality to
Gold-catalyzed synthesis of bicyclo[4.3.0]nonadiene derivatives via tandem 6-endo-dig/Nazarov cyclization of 1,6-allenynes
Lin, Guan-You,Yang, Chun-Yao,Liu, Rai-Shung
, p. 6753 - 6757 (2008/02/10)
(Chemical Equation Presented) Catalytic cyclization of 1,6-allenynes was achieved by AuPPh3SbF6 (5 mol %) in cold CH 2Cl2 (0°C, 0.5-4 h) to form bicyclo[4.3.0]nonadiene products; this cyclization proceeded more
