949094-58-0Relevant academic research and scientific papers
Mechanistic studies of the allylic rearrangements of α-silyloxy allylic silanes to silyloxy vinylic silanes
Kim, Angie I.,Kimmel, Kyle L.,Romero, Antonio,Smitrovich, Jacqueline H.,Woerpel
, p. 6595 - 6598 (2008/02/10)
(Chemical Equation Presented) Mechanistic evidence suggests that the Lewis acid-promoted allylic rearrangement of α-silyloxy allylic silanes proceeds along an ionic reaction pathway involving a contact ion pair. The driving force for this transformation i
