889654-24-4Relevant academic research and scientific papers
Mechanistic studies of the allylic rearrangements of α-silyloxy allylic silanes to silyloxy vinylic silanes
Kim, Angie I.,Kimmel, Kyle L.,Romero, Antonio,Smitrovich, Jacqueline H.,Woerpel
, p. 6595 - 6598 (2008/02/10)
(Chemical Equation Presented) Mechanistic evidence suggests that the Lewis acid-promoted allylic rearrangement of α-silyloxy allylic silanes proceeds along an ionic reaction pathway involving a contact ion pair. The driving force for this transformation i
Stereoselective synthesis of highly substituted γ-lactams by the [3+2] annulation of α-siloxy allylic silanes with chlorosulfonyl isocyanate
Romero, Antonio,Woerpel
, p. 2127 - 2130 (2007/10/03)
A stereoselective synthesis of γ-lactams by the [3+2] annulation of α-siloxy allylic silanes with N-chlorosulfonyl isocyanate (CISO 2NCO) was developed. The use of these allylic silanes allowed for further diastereoselective substitution of the
