94929-12-1

Upstream product

• 19978-61-1 (1,2-bis(diphenylphosphino)ethane)palladium(II) chloride 
• 15843-43-3 silver oxalate 
• 12107-56-1 dichloro(cycloocta-1,5-diene)palladium (II) 

Downstream Products

• 94929-16-5 {Pd(1,2-bis(diphenylphosphanyl)ethane)(C₂H₄)} 
• 41449-73-4 (η3-allyl)(bis(diphenylphosphino)ethane)palladium hexafluorophosphate 
• 19978-61-1 (1,2-bis(diphenylphosphino)ethane)palladium(II) chloride 
• 94929-17-6 Pd(C₂F₄)((C₆H₅)2PCH₂CH₂P(C₆H₅)2) 
• 94929-26-7 (C₃H₅)Pd((C₆H₅)2PCH₂CH₂P(C₆H₅)2)⁽¹⁺⁾*OC₂H₅^(1-) = [(C₃H₅)Pd((C₆H₅)2PCH₂CH₂P(C₆H₅)2)][OC₂H₅] 
• 94929-20-1 Pd(C₆H₅CCC₆H₅)((C₆H₅)2PCH₂CH₂P(C₆H₅)2) 
• 94929-24-5 (C₃H₅)Pd((C₆H₅)2PCH₂CH₂P(C₆H₅)2)⁽¹⁺⁾*OC₆H₅^(1-) = [(C₃H₅)Pd((C₆H₅)2PCH₂CH₂P(C₆H₅)2)][OC₆H₅] 
• 94929-25-6 (C₃H₅)Pd((C₆H₅)2PCH₂CH₂P(C₆H₅)2)⁽¹⁺⁾*OH^(1-) = [(C₃H₅)Pd((C₆H₅)2PCH₂CH₂P(C₆H₅)2)]OH 
• 479072-99-6 [(diphenylphosphinoethane)PdGe(N(SiMe₃)2)2]2 
• 479072-98-5 [(diphenylphosphinoethane)PdGe(N(SiMe₃)2)2] 

Relevant academic research and scientific papers

Photochemical reactions of diphosphineplatinum(II) oxalate complexes

Irradiation at 254 nm of CH3CN/C6H6 or PhCn solutions of produces 2 equiv. of CO2, and in the presence of PhCl or PhI yields .With CO or PhCCPh the products are or CPh)(dppe)>, but in the latter case extended photolysis yields CPh)(dppe)>.Photolysis in the presence of H2 gives a mixture of the + and + cations.Simple elimination of CO2 does not occur in all cases, as illustrated by the formation of when is photolyzed in the presence of methanol.Photochemical reactions of the related complexes (L2 = dppm, dcpe) are also described.

Photochemical generation of bis(phosphine)palladium and bis(phosphine)platinum equivalents

Ultraviolet irradiation of oxalato bis(tertiary phosphine) complexes of platinum(II) and palladium(II), Pt(C2O4)L2 and Pd(C2O4)L2, results in the reductive elimination of the oxalate ligand