94929-12-1Relevant articles and documents
Photochemical reactions of diphosphineplatinum(II) oxalate complexes
Anderson, Gordon K.,Lumetta, Gregg J.,Siria, Jeffrey W.
, p. 253 - 259 (2007/10/02)
Irradiation at 254 nm of CH3CN/C6H6 or PhCn solutions of produces 2 equiv. of CO2, and in the presence of PhCl or PhI yields .With CO or PhCCPh the products are or CPh)(dppe)>, but in the latter case extended photolysis yields CPh)(dppe)>.Photolysis in the presence of H2 gives a mixture of the + and + cations.Simple elimination of CO2 does not occur in all cases, as illustrated by the formation of when is photolyzed in the presence of methanol.Photochemical reactions of the related complexes (L2 = dppm, dcpe) are also described.
Photochemical generation of bis(phosphine)palladium and bis(phosphine)platinum equivalents
Paonessa, Ralph S.,Prignano, Andrea L.,Trogler, William C.
, p. 647 - 657 (2008/10/08)
Ultraviolet irradiation of oxalato bis(tertiary phosphine) complexes of platinum(II) and palladium(II), Pt(C2O4)L2 and Pd(C2O4)L2, results in the reductive elimination of the oxalate ligand