94929-12-1

Basic information

• Product Name: (bis(diphenylphosphino)ethane)(oxalato)palladium(II)
• Synonyms: (bis(diphenylphosphino)ethane)(oxalato)palladium(II)
• CAS NO: 94929-12-1
• Molecular Weight: 592.864
• Mol File: 94929-12-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (bis(diphenylphosphino)ethane)(oxalato)palladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: (bis(diphenylphosphino)ethane)(oxalato)palladium(II)(94929-12-1)
• EPA Substance Registry System: (bis(diphenylphosphino)ethane)(oxalato)palladium(II)(94929-12-1)

Safety Data

• Hazardous Substances Data: 94929-12-1(Hazardous Substances Data)

Upstream product

• 12107-56-1 dichloro(cycloocta-1,5-diene)palladium (II) 
• 19978-61-1 (1,2-bis(diphenylphosphino)ethane)palladium(II) chloride 
• 15843-43-3 silver oxalate 

Downstream Products

• 94929-25-6 (C₃H₅)Pd((C₆H₅)2PCH₂CH₂P(C₆H₅)2)⁽¹⁺⁾*OH^(1-) = [(C₃H₅)Pd((C₆H₅)2PCH₂CH₂P(C₆H₅)2)]OH 
• 479072-99-6 [(diphenylphosphinoethane)PdGe(N(SiMe₃)2)2]2 
• 479072-98-5 [(diphenylphosphinoethane)PdGe(N(SiMe₃)2)2] 
• 94929-24-5 (C₃H₅)Pd((C₆H₅)2PCH₂CH₂P(C₆H₅)2)⁽¹⁺⁾*OC₆H₅^(1-) = [(C₃H₅)Pd((C₆H₅)2PCH₂CH₂P(C₆H₅)2)][OC₆H₅] 
• 94929-20-1 Pd(C₆H₅CCC₆H₅)((C₆H₅)2PCH₂CH₂P(C₆H₅)2) 
• 94929-26-7 (C₃H₅)Pd((C₆H₅)2PCH₂CH₂P(C₆H₅)2)⁽¹⁺⁾*OC₂H₅^(1-) = [(C₃H₅)Pd((C₆H₅)2PCH₂CH₂P(C₆H₅)2)][OC₂H₅] 
• 94929-17-6 Pd(C₂F₄)((C₆H₅)2PCH₂CH₂P(C₆H₅)2) 
• 19978-61-1 (1,2-bis(diphenylphosphino)ethane)palladium(II) chloride 
• 41449-73-4 (η3-allyl)(bis(diphenylphosphino)ethane)palladium hexafluorophosphate 
• 94929-16-5 {Pd(1,2-bis(diphenylphosphanyl)ethane)(C₂H₄)} 

Relevant articles and documents

Photochemical reactions of diphosphineplatinum(II) oxalate complexes

Irradiation at 254 nm of CH3CN/C6H6 or PhCn solutions of produces 2 equiv. of CO2, and in the presence of PhCl or PhI yields .With CO or PhCCPh the products are or CPh)(dppe)>, but in the latter case extended photolysis yields CPh)(dppe)>.Photolysis in the presence of H2 gives a mixture of the + and + cations.Simple elimination of CO2 does not occur in all cases, as illustrated by the formation of when is photolyzed in the presence of methanol.Photochemical reactions of the related complexes (L2 = dppm, dcpe) are also described.