94943-07-4

Upstream product

• 108-24-7 acetic anhydride 
• 74517-36-5 tetra-O-acetyl-(1,2/3,4,5)-2-bromo-5-hydroxymethyl-1,3,4-cyclohexanetriol 
• 74517-36-5 tetra-O-acetyl-(1,3,5/2,4)-2-bromo-5-hydroxymethyl-1,3,4-cyclohexanetriol 
• 10226-73-0 (1R,2R,3S,4R,5R)-5-Hydroxymethyl-cyclohexane-1,2,3,4-tetraol 
• 64589-25-9 (+/-)-2exo,3exo-diacetoxy-5exo-acetoxymethyl-7-oxabicyclo<2.2.1>heptane 
• 64589-25-9 (+/-)-2exo,3exo-diacetoxy-5endo-acxetoxymethyl-7-oxabicyclo<2.2.1>heptane 
• 64589-25-9 exo-2, endo-3-diacetoxy-endo-5-acetoxymethyl-7-oxabicyclo[2.2.1]heptane 
• 108713-95-7 2-[(2S,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentylidene]-malonic acid dimethyl ester 
• 108713-96-8 2-[(2S,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentyl]-malonic acid dimethyl ester 
• 16703-82-5 DL-2,5-Diacetoxy-1-acetoxymethyl-cyclohexen-⁽³⁾ 
• 15910-11-9 1,4-diacetoxy 1,3-butadiene 
• 16656-59-0 Pseudo-β-DL-gulopyranose-triacetat; DL-1-Acetoxymethyl-2,5-diacetoxy-3,4-dihydroxy-cyclohexan 
• 69982-68-9 endo-3-acetoxy-endo-5-acetoxymethyl-exo-2-bromo-7-oxabicyclo<2.2.1>heptane 
• 108794-49-6 (1R,2S,6R,7S,8R)-4,4-Dimethyl-3,5,9-trioxa-tricyclo[6.2.1.0^2,6]undecan-7-ol 

Downstream Products

• 10226-73-0 Pseudo-α-DL-talopyranose; 2c,3c,4c,5t-Tetrahydroxy-1-cyclohexan-methanol 
• 10226-80-9 (+/-)-1r-Triphenylmethoxymethyl-2c,3c,4c,5t-tetraacetoxy-cyclohexan 
• 10226-73-0 Pseudo-β-DL-gulopyranose; DL-1-Hydroxymethyl-2,3,4,5-tetrahydroxy-cyclohexan 
• 10226-73-0 DL-(1,2,4/3,5)-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 81307-66-6 (1S,2S,3S,4S,5S)-pseudo-β-L-altrose 
• 10226-73-0 DL-(1,2/3,4,5)-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 97321-82-9 (1SR,3SR,5SR,8RS,10SR,12RS)-5,12-diphenyl-4,6,11,13-tetraoxatricyclo<8.3.0.0^3,8>tridecan-2-one 
• 97321-80-7 (1SR,2RS,3SR,5SR,8RS,10SR,12RS)-5,12-diphenyl-4,6,11,13-tetraoxatricyclo<8.3.0.0^3,8>tridecan-2-ol 
• 97321-80-7 (1SR,2SR,3SR,5SR,8RS,10SR,12RS)-5,12-diphenyl-4,6,11,13-tetraoxatricyclo<8.3.0.0^3,8>tridecan-2-ol 
• 97321-80-7 (1SR,2SR,3SR,5SR,8RS,10SR,12SR)-5,12-diphenyl-4,6,11,13-tetraoxatricyclo<8.3.0.0^3,8>tridecan-2-ol 
• 10226-73-0 DL-(1,2,4,5/3)-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 10226-73-0 DL-(1,3,5/2,4)-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 80065-31-2 DL-tetra-O-acetyl-(1,3,5/2,4)-5-bromomethyl-1,2,3,4-cyclohexanetetrol 
• 60543-79-5 DL-tetra-O-acetyl-(1,3,5/2,4)-5-methyl-1,2,3,4-cyclohexanetetrol 

Relevant academic research and scientific papers

Synthesis of some carbahexopyranoses using Mn/CrCl3 mediated domino reactions and ring closing metathesis

An efficient and common method for the synthesis of 5a-carba-α-D-mannopyranose 5, 5a-carba-β-D-mannopyranose 6, (+) methyl shikimate 9, (+) methyl-5-epi-shikimate 10, validamine analogue 15 and valiolamine analogue 16 from D-mannose, formal synthesis of T

A general norbornyl based synthetic approach to carbasugars and 'confused' carbasugars

The norbornyl system has been recognized simply as a 'locked' carbasugar and a short, general approach to carbasugars and their new siblings, 'confused' carbasugars, from readily available 7-ketonorbornanes is reported.

A norbornyl route to cyclohexitols: Structural diversity in fragmentation through functional group switching. Synthesis of α- and β- galactose, α-talose and α-fucopyranose carbasugars

A novel fragmentation sequence has been executed within the norbornane system, involving C1-C7 bond scission, to extract a versatile, highly functionalized cyclohexanoid moiety. Its further evolution towards a range-of carbasugars is described. (C) 2000 Elsevier Science Ltd.

Desymmetrisation of dienylsilanes. Stereoselective access to cyclitols and carba-sugars

The diastereo- and enantioselective functionalisation of 1,4-cyclohexadienylsilanes using Sharpless asymmetric dihydroxylation and aminohydroxylation offers a straightforward access to various classes of potent inhibitors of glycosidases. The scope and limitation of this desymmetrisation method is illustrated here with the synthesis of various conduritols, carba-sugars and carba-C-disaccharides.

Synthesis of pseudo-sugars based on desymmetrization of dienylsilanes

A synthesis of pseudo-sugars using the desymmetrization of a dienylsilane, followed by a stereocontrolled introduction of the hydroxymethyl group at C5, is described. The CH2OH group at C5 was elaborated using either a regioselective cyclopropane-ring opening or a [2,3]-Wittig rearrangement.

A Novel Transformation of Four Aldoses to Some Optically Pure Pseudohexopyranoses and a Pseudopentofuranose, Carboxylic Analogues of Hexopyranoses and Pentofuranose. Synthesis of Derivatives of (1S,2S,3R,4S,5S)-, (1S,2S,3R,4R,5S)-, (1R,2R,3R,4R,5S)-, (1S,

Knoevenagel reactions with dimethyl malonate of the suitably protected acylic aldehydes 6, 20, 34, and 46, which were prepared from D-ribose, D-xylose, D-arabinose, and D-erythrose, respectively, proceeded smoothly to provide α,β-unsaturated diesters 7, 2

SYNTHESIS OF (1,2,3,4,5/0)-5-HYDROXYMETHYL-1,2,3,4-CYCLOHEXANETETROL: PSEUDO-β-DL-TALOPYRANOSE

The remaining unknown diastereoisomer of 5-hydroxymethyl-1,2,3,4-cyclohexanetetrol with the (1,2,3,4,5/0)-configuration has been synthesised as the pentaacetate from DL-(1,2/3,4,5)-1,3,4-triacetoxy-5-acetoxymethyl-2-bromocyclohexane.In addition, a new syn

SYNTHESIS OF METHYL DL-(1,3/2,4,5)- AND DL-(1,3,4/2,5)-2,3,4,5-TETRAHYDROXYCYCLOHEXANE-1-CARBOXYLATES

Two new diastereoisomers of the pseudo-hexuronate methyl 2,3,4,5-tetrahydroxycyclohexane-1-carboxylate, having (1,3/2,4,5)- (8) and (1,3,4/2,5)-configurations (16), have been synthesized from the readily available bromo-lactone (1) of the endo-adduct of f