94898-39-2

Upstream product

• 108713-96-8 2-[(2S,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentyl]-malonic acid dimethyl ester 
• 108713-95-7 2-[(2S,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentylidene]-malonic acid dimethyl ester 
• 108813-43-0 (3R,4R,5S)-3,4,5-tris(benzyloxy)-1-cyclohexene-1-methanol 
• 94898-37-0 methyl (3R,4R,5S)-3,4,5-tris(benzyloxy)-1-cyclohexene-1-carboxylate 
• 108813-40-7 dimethyl (2S,3R,4R,5S)-2-acetoxy-3,4,5-tris(benzyloxy)cyclohexane-1,1-dicarboxylate 
• 108813-41-8 dimethyl (2R,3R,4R,5S)-2-acetoxy-3,4,5-tris(benzyloxy)cyclohexane-1,1-dicarboxylate 
• 108714-00-7 2-[(2R,3S,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentyl]-malonic acid dimethyl ester 
• 108713-99-1 2-[(2R,3S,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentylidene]-malonic acid dimethyl ester 
• 108813-44-1 (3R,4S,5R)-3,4,5-tris(benzyloxy)-1-cyclohexene-1-methanol 
• 96290-96-9 methyl (3R,4S,5R)-3,4,5-tris(benzyloxy)-1-cyclohexene-1-carboxylate 
• 96290-94-7 dimethyl (2S,3R,4S,5R)-2-acetoxy-3,4,5-tris(benzyloxy)cyclohexane-1,1-dicarboxylate 
• 105368-81-8 (3R,4S,5S)-3,4,5-tris(benzyloxy)-1-cyclohexene-1-methanol 
• 125258-11-9 DL-(1,2,4/3,5)-1,2,3-tri-O-benzyl-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 100-39-0 benzyl bromide 

Downstream Products

• 10226-79-6 (1R,2R,3R,4R,5S)-2,3,4,5-tetraacetoxy-1-(acetoxymethyl)cyclohexane, pseudo-α-D-altropyranose pentaacetate 
• 108813-47-4 (1S,2S,3R,4R,5S)-2,3,4,5-tetraacetoxy-1-(acetoxymethyl)cyclohexane, pseudo-β-L-glucopyranose pentaacetate 
• 108813-49-6 (1S,2S,3R,4S,5R)-2,3,4,5-tetraacetoxy-1-(acetoxymethyl)cyclohexane, pseudo-α-L-mannopyranose pentaacetate 
• 105368-83-0 (1S,2S,3R,4S,5S)-2,3,4,5-tetraacetoxy-1-(acetoxymethyl)cyclohexane, pseudo-β-L-mannopyranose pentaacetate 
• 94943-06-3 (1S,2S,3S,4R,5R)-1,2,3,4-tetraacetoxy-5-acetoxymethylcyclohexane 
• 81307-66-6 (1S,2S,3S,4R,5R)-pseudo-α-D-glucose 
• 102629-12-9 (1R,2S,3S,4S,5S)-5-(acetoxymethyl)cyclohexane-1,2,3,4-tetrayl tetraacetate 
• 81307-66-6 (1S,2S,3S,4S,5S)-pseudo-β-L-altrose 
• 94943-07-4 (1S,2S,3S,4S,5S)-5-(acetoxymethyl)cyclohexane-1,2,3,4-tetrayl tetraacetate 
• 102629-13-0 (1S,2S,3S,4S,5R)-2,3,4,5-tetrahydroxy-1-hydroxymethylcyclohexane 

Relevant academic research and scientific papers

A Novel Transformation of Four Aldoses to Some Optically Pure Pseudohexopyranoses and a Pseudopentofuranose, Carboxylic Analogues of Hexopyranoses and Pentofuranose. Synthesis of Derivatives of (1S,2S,3R,4S,5S)-, (1S,2S,3R,4R,5S)-, (1R,2R,3R,4R,5S)-, (1S,

Knoevenagel reactions with dimethyl malonate of the suitably protected acylic aldehydes 6, 20, 34, and 46, which were prepared from D-ribose, D-xylose, D-arabinose, and D-erythrose, respectively, proceeded smoothly to provide α,β-unsaturated diesters 7, 2

Construction of an Optically Active 7-Oxabicyclonon-4-en-3-one. Skeleton from D-Glucose, and Its Transformation to Some Pseudo-Hexopyranoses

A versatile chiral compound, (1R,6R,8R,9R)-8,9-isopropylidenedioxy-7-oxabicyclonon-4-en-3-one (6), was efficiently synthesized from D-glucose.The synthesis featured an intramolecular aldol cyclization of 3-C-acetylmethyl-3-deoxy-1,2-O-isopropyliden

A NEW TRANSFORMATION OF ALDOSE DERIVED SYNTHONS TO PSEUDO-HEXOPYRANOSE OR PSEUDO-PENTOFURANOSE DERIVATIVES

The D-ribose or D-erythrose derived acyclic synthon, which possesses a 2-malonyl carbon chain at C-1 position, was cyclized stereoselectively to a six- or five-membered carbocycle.Those carbocycles were converted into pseudo-β-L-mannopyranose derivatives

A NOVEL SYNTHESIS OF PSEUDO-α-L-ALTROPYRANOSE FROM D-GLUCOSE

(1R,6R,8R,9R)-8,9-Isopropylidenedioxy-3-oxo-7-oxabicyclo-non-4-ene, a highly functionalized bicyclic compound, has been synthesized from D-glucose employing an intramolecular aldol condensation as the key reaction, and a transformation of it into p

SYNTHESIS OF OPTICALLY ACTIVE PSEUDO-α-D-GLUCOSE AND PSEUDO-β-L-ALTROSE

Optically active two pseudo-sugars, pseudo-α-D-glucose and pseudo-β-L-altrose have been synthesized by cyclization of 2,3,4-tri-O-benzyl-5-deoxy-5-iodo-L-arabinose with dimethyl malonate in the presence of sodium hydride as a key reaction.