95-06-7 Hazards Identification
Signal:
Danger
GHS Hazard Statements:
H302: Harmful if swallowed [Warning Acute toxicity, oral]
H350: May cause cancer [Danger Carcinogenicity]
H400: Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
H410: Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]
Precautionary Statement Codes:
P203, P264, P270, P273, P280, P301+P317, P318, P330, P391, P405, and P501
Hazard Classes and Categories:
Carc. 1B
Acute Tox. 4 *
Aquatic Acute 1
Aquatic Chronic 1
Acute Tox. 4 (100%)
Carc. 1B (100%)
Aquatic Acute 1 (100%)
Aquatic Chronic 1 (100%)
Carcinogenicity - category 1B
Acute toxicity - category 4
Hazardous to the aquatic environment (acute) - category 1
Hazardous to the aquatic environment (chronic) - category 1
Acute toxicity (Oral) - Category 4
Acute toxicity (Dermal) - Category 5
Skin corrosion/irritation - Category 2
Serious eye damage/eye irritation - Category 2A
Carcinogenicity - Category 2
Specific target organ toxicity - Repeated exposure - Category 2 (kidney)
Carcinogens, Flammable - 2nd degree
Hazards Summary:
May cause skin and eye irritation on prolonged contact; [Merck Index] Although marked adverse effects may follow injection of EBDC compounds into animals, systemic toxicity by oral and dermal routes is generally low. [EPA Pesticides, p. 144] Several of the dialkyldithiocarbamates are known skin sensitizers; See Carba mix.
95-06-7 Usage
Air & Water Reactions
Insoluble in water. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.
Reactivity Profile
SULFALLATE is incompatible with strong oxidizing agents .Also incompatible with alkalis. .
Fire Hazard
SULFALLATE is probably combustible.
Safety Profile
Confirmed carcinogen
with experimental carcinogenic data.
Moderately toxic by ingestion and skin
contact. Mutation data reported. An
herbicide. When heated to decomposition it
emits very toxic fumes of Cl-, NOx, and
SOx. See also ALLYL COMPOUNDS,
CARBAMATES, and ESTERS.
Potential Exposure
A dithiocarbamate. The major use for sulfallate in the United States is as a preemergent selective herbicide to control certain annual grasses and broadleaf weeds around vegetable and fruit crops. Sulfallate has also been used for weed control among shrubbery and ornamental plants. Some dithiocarbamates have been used as rubber components
Carcinogenicity
Sulfallate is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
Shipping
UN2771 Dithiocarbamate and Thiocarbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
Incompatibilities
Dithiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of dithiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine.Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of dithiocarbamate with aldehydes, nitrides, and hydrides. Dithiocarbamate are incompatible with acids, peroxides, and acid halides.
Waste Disposal
Small amounts may be decomposed by strong oxidizing agent. Large amounts should be incinerated in a unit with effluent gas scrubbing.
Check Digit Verification of cas no
The CAS Registry Mumber 95-06-7 includes 5 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 2 digits, 9 and 5 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 95-06:
(4*9)+(3*5)+(2*0)+(1*6)=57
57 % 10 = 7
So 95-06-7 is a valid CAS Registry Number.
InChI:InChI=1/C8H14ClNS2/c1-4-10(5-2)8(11)12-6-7(3)9/h3-6H2,1-2H3
95-06-7Relevant academic research and scientific papers
Triazolecarboxamide herbicides
-
, (2008/06/13)
Compounds of the formula: STR1 wherein X is O or S; R and R1 are substituted or unsubstituted alkyl, alkenyl, alkynyl or cycloalkyl or R and R1 may be joined to form a heterocyclic ring; R2 is substituted or unsubstituted cycloalkyl; and n is 0, 1 or 2 are disclosed as well as their postemergence and preemergence selective herbicide use against both monocot and dicot weeds in crops such as sugarbeets, cotton, soybeans and rice.
