95-11-4

Basic information

• Product Name: 5-Norbornene-2-carbonitrile
• Synonyms: 5-NORBORNENE-2-CARBONITRILE;5-NORBORNENE-2-CARBONITRILE, 98%, MIXTUR E OF ISOMERS;5-norbornene-2-carbonitrile, mixture of isomers;2-Cyano-5-norbornene;2-Cyanobicyclo[2.2.1]hept-5-ene;5-Cyano-2-norbornene;Bicyclo[2.2.1]-5-hepten-2-carbonitrile;5-Norbornene-2-carbonitrile, 98%, mixture of endo and exo
• CAS NO: 95-11-4
• Molecular Formula: C₈H₉N
• Molecular Weight: 119.16
• EINECS: 202-391-5
• Product Categories: Norbornene Derivatives;C8 to C9;Cyanides/Nitriles;Nitrogen Compounds;Building Blocks;C8 to C9;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Isoquinolines ,Quinolines ,Quinaldines
• Mol File: 95-11-4.mol
• Article Data: 23

Chemical Properties

• Melting Point: 12-14 °C(lit.)
• Boiling Point: 82-86 °C10 mm Hg(lit.)
• Flash Point: 150 °F
• Appearance: clear colourless liquid
• Density: 0.999 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.254mmHg at 25°C
• Refractive Index: n20/D 1.488(lit.)
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 5-Norbornene-2-carbonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Norbornene-2-carbonitrile(95-11-4)
• EPA Substance Registry System: 5-Norbornene-2-carbonitrile(95-11-4)

Safety Data

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36/37/39-36/37
• WGK Germany: 3
• RTECS: RB7930000
• Hazardous Substances Data: 95-11-4(Hazardous Substances Data)

Usage

Chemical Properties

clear colourless liquid

Uses

Bicyclo[2.2.1]hept-2-ene-5-carbonitrile is used in method for continuously preparing cyanonorbornene by using microchannel reactor.

General Description

The hydrogenation of 5-norbornene-2-carbonitrile was studied using real-time mass spectrometric analysis.

InChI:InChI=1/C8H9N/c9-5-8-4-6-1-2-7(8)3-6/h1-2,6-8H,3-4H2

Upstream product

• 542-92-7 cyclopenta-1,3-diene 
• 107-13-1 acrylonitrile 
• 1147550-11-5 ammonium thiocyanate 
• 90086-80-9 bicyclo<2.2.1>hept-5-ene-2-carboxaldehyde oxime 
• 67403-76-3 2,6-dimethyl-non-2-ene 
• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 
• 77-73-6 bi(cyclopentadiene) 
• 5453-80-5 5-Norbornene-2-carboxaldehyde 

Downstream Products

• 5257-46-5 (bicyclo<2.2.1>heptene-5 yle-2)-1 propanone-1, endo 
• 5257-46-5 1-bicyclo(2.2.1)-hept-5-en-2-yl propanone 
• 2234-26-6 2-norbornanecarbonitrile 
• 694-98-4 norborn-5-en-2-one 
• 18776-20-0 (1S,2R,4S,5S)-3-Oxa-tricyclo[3.2.1.0^2,4]octane-6-carbonitrile 
• 256398-13-7 3-endo-acetyl-6-cyanotricyclo[3.2.1.0^2,4]octane 
• 256398-13-7 3-exo-acetyl-6-cyanotricyclo[3.2.1.0^2,4]octane 
• 14370-50-4 2-Aminomethylbicyclo<2.2.1>heptane 
• 10171-76-3 di(2R-exo-norbornylmethyl)amine 
• 84898-04-4 2-cyano-5-formylbicyclo[2.2.1]heptane 
• 84898-05-5 2-cyano-6-formylbicyclo[2.2.1]heptane 
• 102939-71-9 [(1R,2R,4S,5S,6S)-6-(3-Methoxy-benzyl)-3-oxa-tricyclo[3.2.1.0^2,4]oct-6-yl]-propynoic acid methyl ester 
• 102939-73-1 [(1S,2R,4S)-2-(3-Methoxy-benzyl)-bicyclo[2.2.1]hept-5-en-2-yl]-propynoic acid methyl ester 
• 102939-75-3 (1S,4S,5R)-5-(2,2-Dibromo-vinyl)-5-(3-methoxy-benzyl)-bicyclo[2.2.1]hept-2-ene 

Relevant articles and documents

PROCESS FOR PRODUCING CYANONORBORNENE

A process for producing cyanonorbornene of the present invention includes Step 1 of preparing a mixture solution including 0.5% by weight to 28% by weight of methyl bicyclononadiene, with respect to a total amount of 100% by weight of dicyclopentadiene, acrylonitrile, and the methyl bicyclononadiene, in a container, and Step 2 of reacting the bicyclopentadiene with the acrylonitrile in the presence of the methyl bicyclononadiene, in the mixture solution.

Thiocyanate radical mediated dehydration of aldoximes with visible light and air

We developed a new means of activating aldoximes by an in situ generated thiocyanate radical from ammonium thiocyanate and molecular oxygen at room temperature. With a catalytic amount of organic dye aizenuranine as the photocatalyst, the dehydration of aldoximes proceeds smoothly under visible light irradiation, providing a simple to handle, excellent functional group tolerance, and metal-free protocol for a wide range of nitriles.

METHOD FOR PRODUCING ALDEHYDE COMPOUND

A preparation method of an aldehyde compound of the present invention includes a step of reacting a compound represented by the following general formula (a1) with hydrogen and carbon monoxide in the presence of a metal compound including 0.01 ppmmol to 10 ppmmol of a metal belonging to Groups 8 to 10 with respect to 1 mole of the compound and a phosphorus compound, and in the step, the amount of acrylonitrile included in the compound represented by the general formula (a1) is equal to or less than 200-fold by mole with respect to 1 mole of the metal belonging to Groups 8 to 10.