111099-08-2

Basic information

• Product Name: endo (methyl-2 phenyl-3 trimethylsiloxy-3 propanone-1 yl)-5 bicyclo<2.2.1> heptene-2
• CAS NO: 111099-08-2
• Molecular Weight: 328.527
• Mol File: 111099-08-2.mol

Chemical Properties

• CAS DataBase Reference: endo (methyl-2 phenyl-3 trimethylsiloxy-3 propanone-1 yl)-5 bicyclo<2.2.1> heptene-2(CAS DataBase Reference)
• NIST Chemistry Reference: endo (methyl-2 phenyl-3 trimethylsiloxy-3 propanone-1 yl)-5 bicyclo<2.2.1> heptene-2(111099-08-2)
• EPA Substance Registry System: endo (methyl-2 phenyl-3 trimethylsiloxy-3 propanone-1 yl)-5 bicyclo<2.2.1> heptene-2(111099-08-2)

Safety Data

• Hazardous Substances Data: 111099-08-2(Hazardous Substances Data)

Upstream product

• 95-11-4 bicyclo<2.2.1>heptene-5 carbonitrile-2 
• 5257-46-5 (bicyclo<2.2.1>heptene-5 yle-2)-1 propanone-1, endo 
• 95-11-4 bicyclo[2.2.1]hept-5-ene-2-carbonitrile 
• 75-77-4 chloro-trimethyl-silane 
• 100-52-7 benzaldehyde 
• 111099-03-7 endo (hydroxy-3 methyl-2 phenyl-3 propanone-1 yl-1)-5 bicyclo<2.2.1>heptene-2 
• 5257-46-5 1-bicyclo(2.2.1)-hept-5-en-2-yl propanone 

Downstream Products

• 111099-13-9 anti 4,5 methyl-4 phenyl-5 trimethylsiloxy-5 pentene-1 one-3 
• 111099-13-9 syn 4,5 methyl-4 phenyl-5 trimethylsiloxy-5 pentene-1 one-3 
• 111099-13-9 methyl-4 phenyl-5 trimethylsiloxy-5 pentene-1 one-3 

Relevant articles and documents

ALDOLISATION STEREOCONTROLEE PAR UN GROUPE TERMOLABILE. SYNTHESE STEREOSELECTIVE DE COMPOSES POSSEDANT TROIS CARBONES ASYMMETRIQUES CONSECUTIFS.

The bulkiness of thermolabile norbornenyl and oxanorbornenyl groups has been used to induce good to excellent syn diastereoselective aldol condensations between Diels-Alder adducts of α,β-ethylenic ketones and various aldehydes.The aldols thus obtained gi

STEREOSELECTIVE ALDOL CONDENSATIONS INDUCED BY A THERMOLABILE GROUP.

Diastereoselective aldol condensations between exo, endo and 2-methyl endo bicyclo-5-hepten-2-yl ethyl ketones and aldehydes are achieved via the ketones Z-lithium enolates prepared with lithium hexamethyldisilazide.The aldols thus obtained give rise by a retro Diels-Alder reaction to syn α-methyl-β-siloxy-α'-ethylenic ketones of potential value for polyhydroxylated natural product synthesis.