95054-37-8Relevant academic research and scientific papers
An oxidative rearrangement of 6-phenylbicyclo[3.2.0]heptan-6-ol to 1,1′-biphenyl-carbaldehydes: A mechanistic study
Ceylan, Mustafa,Findik, Esra,Secen, Hasan
experimental part, p. 559 - 568 (2009/02/07)
Acid-catalyzed rearrangement of 6-phenylbicyclo[3.2.0]heptan-6-ol gave 1,1′-biphenyl and 1,1′-biphenyl-carbaldehydes in small amounts as well as the expected rearrangement products. A detailed study of the reaction mechanism revealed that the conversion occurs via an oxidative process through the consecutive formation of cycloheptadienes, cycloheptatrienes, and 1,1′-biphenyls. The acid-catalyzed rearrangement of 6-phenylbicyclo[3.2.0] hept-2-en-6-ols gave 1- and 2-phenylcycloheptatrienes directly, from which 1,1′-biphenyl and 1,1′-biphenyl-carbaldehydes were obtained by oxidation.
ADDITION REACTIONS TO BICYCLOBUTANE DERIVATIVES X. THE REGIOSELECTIVITY AND STEREOSELECTIVITY OF OPENING OF 1-PHENYLTRICYCLO2,7>HEPTANE BY ELECTROPHILIC REAGENTS
Razin, V. V.,Zadonskaya, N. Yu.,Shamurzaev, Kh. T.
, p. 1093 - 1100 (2007/10/02)
The products from the reaction of 1-phenyltricyclo2,7>heptane with sulfuric acid, mercury(II) acetate, and N-bromosuccinimide in an aqueous and/or methanol medium were studied.The addition of methanol catalyzed by sulfuric acid takes pl
SULFIDE EXTRUSION FROM THE METHYLSULFONIUM SALTS OF 8-THIABICYCLO-OCT-2-ENES AND THE RELATED SULFONIUM SALTS BY METHYLLITHIUM
Uyehara, Tadao,Takahashi, Masayuki,Kato, Tadahiro
, p. 3999 - 4002 (2007/10/02)
The methylsulfonium salts of 2-methylene-8-thiabicyclooctane and 8-thiabicyclooct-2-enes underwent sulfide extrusion by methyllithium to give dimethyl sulfide and the hydrogen shift products (cycloheptadienes) and/or the closure products (bi
