950593-84-7Relevant academic research and scientific papers
Rhenium-catalyzed synthesis of naphthalene derivatives via insertion of aldehydes into a C-H bond
Kuninobu, Yoichiro,Nishina, Yuta,Takai, Kazuhiko
, p. 8463 - 8468 (2007)
A rhenium complex, [ReBr(CO)3(THF)]2, catalyzed reactions of aromatic ketimines and aldehydes with dienophiles, followed by dehydration, to give naphthalene derivatives in good to excellent yields. This reaction proceeds via C-H bond activation, insertion of an aldehyde, intramolecular nucleophilic cyclization, reductive elimination, elimination of aniline and Diels-Alder reaction. After dehydration, naphthalene derivatives were formed.
THERMOCHEMICAL AND KINETIC INVESTIGATION OF DIELS-ALDER REACTIONS WITH ETHYLENIC AND ACETYLENIC DIENOPHILES
Samuilov, Ya., D.,Nurullina, R. L.,Konovalov, A. I.
, p. 1285 - 1289 (2007/10/02)
A thermochemical and kinetic investigation of the reactions of a series of acetylenic and ethylenic compounds with 1,3-diphenylisobenzofuran was undertaken.It was shown that the reactions of the acetylenic dienophiles are more exothermic than those of the
COMPARATIVE INVESTIGATION OF THE REACTIVITY OF ETHYLENIC AND ACETYLENIC DIENOPHILES IN THE DIELS-ALDER REACTION
Samuilov, Ya. D.,Nurullina, R. L.,Konovalov, A. I.
, p. 1988 - 1995 (2007/10/02)
The reactivity of substituted phencyclones, anthracenes, and a series of other dienes in the Diels-Alder reaction with dimethyl fumarate, dimethyl acetylenedicarboxylate, 1-hexene, and 1-hexyne and with certain monosubstituted ethylenic and acetylenic die
