950602-62-7

Upstream product

• 942043-27-8 4-methylphenyl 2,3,4,6-tetra-O-trimethylsilyl-1-thio-α-D-mannopyranoside 
• 100-39-0 benzyl bromide 
• 755002-33-6 para-tolyl (R)-4,6-O-benzylidene-1-thio-α-D-mannopyranoside 
• 457931-46-3 4-methylphenyl 1-thio-α-D-mannopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 

Downstream Products

• 950602-59-2 p-tolyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside 
• 1235137-36-6 tolyl 2,3-di-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->3)-2-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside 
• 1369224-26-9 p-methylphenyl 6-O-(6-O-acetyl-3-O-benzoyl-2,4-di-O-benzyl-α-D-mannopyranosyl)-3-O-benzoyl-2,4-di-O-benzyl-1-thio-α-D-mannopyranoside 
• 1369224-27-0 p-methylphenyl 6-O-(2,4-di-O-benzyl-α-D-mannopyranosyl)-2,4-di-O-benzyl-1-thio-α-D-mannopyranoside 
• 1369224-14-5 p-methylphenyl 6-O-(2,4-di-O-benzyl-3,6-di-O-propargyl-α-D-mannopyranosyl)-2,4-di-O-benzyl-3-O-propargyl-1-thio-α-D-mannopyranoside 
• 1369224-18-9 p-methylphenyl 3-O-benzoyl-2,4-di-O-benzyl-1-thio-α-D-mannopyranoside 
• 1369224-24-7 p-methylphenyl 6-O-acetyl-3-O-benzoyl-2,4-di-O-benzyl-1-thio-α-D-mannopyranoside 
• 1369224-21-4 p-methylphenyl 3-O-benzoyl-2-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside 
• 950602-71-8 octyl 2-O-benzyl-4,6-O-benzylidene-3-deoxy-α-D-arabino-hexopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 950602-70-7 octyl 2-O-benzyl-4,6-O-benzylidene-3-O-(methylthio)thiocarbonyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 950602-67-2 octyl 2-O-benzyl-4,6-O-benzylidene-3-O-methyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 950602-57-0 octyl 2-O-benzyl-4,6-O-benzylidene-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 950602-65-0 octyl 3-O-acetyl-2-O-benzyl-4,6-O-benzylidene-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 

Relevant academic research and scientific papers

Regioselective and stereoselective benzylidene installation and one-pot protection of d-mannose

Oligosaccharide syntheses are an important source of well-defined sugar constructs particularly needed for the evaluation of structure-activity relationships. The chemical assembly of oligosaccharides requires several building blocks, that is, glycosyl donors and acceptors, which are prepared in multistep processes and in a generally tedious and time-consuming manner. Having developed one-pot procedures meant to minimise the effort in sugar building block preparation, we tackled herein the one-pot preparation of fully protected and 2-, 3-, 4-, and 6-alcohol derivatives of d-mannose, a widely distributed monosaccharide. As a consequence of the hydroxyl group pattern of d-mannose, regioselective and stereoselective benzylidenations were developed and later seamlessly utilised as the first transformation in the one-pot procedure.

Rate-dependent inverse-addition β-selective mannosylation and contiguous sequential glycosylation involving β-mannosidic bond formation

The β-selectivity of mannosy-lation has been found to be dependent on the addition rate of the mannosyl trichloroacetimidate donor in an inverse-addition (I-A) procedure. This rate dependent I-A procedure can improve the selectivity of direct β-mannosylat

Synthesis of deoxy and methoxy analogs of octyl α-d-mannopyranosyl-(1→6)-α-d-mannopyranoside as probes for mycobacterial lipoarabinomannan biosynthesis

A panel of analogs of the disaccharide α-d-Manp-(1→6)-α-d-Manp-OOctyl, a known acceptor substrate for a polyprenol monophosphomannose-dependent α-(1→6)-mannosyltransferase involved in the assembly of the α-(1→6)-linked mannan core of mycobacterial lipoara