950769-07-0Relevant articles and documents
A convenient and efficient method for incorporation of pentafluorosulfanyl (SF5) substituents into aliphatic compounds
Dolbier Jr., William R.,A?t-Mohand, Samia,Schertz, Tyler D.,Sergeeva, Tatiana A.,Cradlebaugh, Joseph A.,Mitani, Akira,Gard, Gary L.,Winter, Rolf W.,Thrasher, Joseph S.
, p. 1302 - 1310 (2006)
Both SF5Cl and SF5Br undergo smooth, high yield addition to alkenes and alkynes under the mild free radical chain reaction conditions of triethylborane initiation at low temperature, although the SF5Br chemistry is somewha
Improved and facile addition reactions of pentafluorosulfanyl bromide
Lim, Dong Sung,Ngo, Silvana C.,Lal, Sankar G.,Minnich, Kristen E.,Welch, John T.
, p. 5662 - 5663 (2008/12/22)
A solution of SF5Br in CCl3F (0.5-1 M) was utilized to effect the addition of pentafluorosulfanyl bromide (SF5Br) to olefins. The reaction of the SF5Br solution in the presence of triethylborane (0.1 equiv) with an olefin over 20 min at 0 °C gave pentafluorosulfanylated compound 2(a-f) in high yield (Table 2). An efficient route for the preparation of synthetically useful SF5-containing esters is also described.
Synthesis of pentafluorosulfuranyl substituted alkanes
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Page/Page column 9-10, (2008/06/13)
Addition of an SF5 group to organic compounds such as alkyl-substituted terminal alkenes, internal alkenes and cycloalkenes via the reaction with SF5Br is effected under liquid phase conditions and generally in the presence of a free
