95087-01-7

Upstream product

• 95086-99-0 methyl 4-O-benzoyl-2,3,6-trideoxy-3-C-methyl-3-trifluoroacetamido-β-L-lyxohexopyranoside 
• 883104-82-3 N-(6-methoxy-8-methyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl)-O-methyl-hydroxylamine 
• 95086-98-9 methyl 4-O-benzoyl-2,3,6-trideoxy-3-C-methyl-3-trifluoroacetamido-α-D-erythro-hex-5-enopyranoside 
• 85687-30-5 methyl 4-O-benzoyl-6-bromo-2,3,6-trideoxy-3-C-methyl-3-(trifluoroacetamido)-α-D-ribo-hexopyranoside 
• 85687-29-2 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-methyl-3-trifluoroacetamido-α-D-ribo-hexopyranoside 
• 65827-66-9 (4aR,6S,8aS)-6-Methoxy-8-methyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ylamine 
• 98758-31-7 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-methyl-3-(trifluoroacetamido)-α-D-ribo-hexopyranoside 
• 883104-83-4 2,2,2-trifluoro-N-methoxy-N-(6-methoxy-8-methyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl)-acetamide 

Downstream Products

• 883104-85-6 Benzoic acid (2S,3S,4S,6R)-6-acetoxy-2,4-dimethyl-4-(2,2,2-trifluoro-acetylamino)-tetrahydro-pyran-3-yl ester 
• 95087-05-1 3'-C-methyldaunorubicin 
• 95087-03-9 4-O-benzoyl-1-O-(4-O-benzoyl-2,3,6-trideoxy-3-C-methyl-3-trifluoroacetamido-α-L-lyxo-hexopyranosyl)-2,3,6-trideoxy-3-C-methyl-3-trifluoroacetamido-α-L-lyxo-hexopyranose 
• 95087-04-0 7-O-<4-O-benzoyl-2,3,6-trideoxy-3-C-methyl-3-trifluoroacetamido-α-L-lyxohexopyranosyl>daunomycinone 
• 95087-02-8 1,5-anhydro-4-O-benzoyl-2,3,6-trideoxy-3-C-methyl-3-trifluoroacetamido-L-lyxo-hex-1-enitol 

Relevant academic research and scientific papers

Synthesis of L-vancosamine derivatives from methyl α-D- mannopyranoside

Concise synthesis of L-vancosamine, the amino sugar constituent of vancomycin and other antibiotics, has been achieved. The key steps include (1) stereoselective addition of methylcerium reagent to oximino ether, and (2) stereoselective hydrogenation of 5

SYNTHESIS AND ANTITUMOR ACTIVITY OF 3'-C-METHYL-DAUNORUBICIN

Reaction of 1,5-anhydro-4-O-benzoyl-2,3,6-trideoxy-3-C-methyl-3-trifluoroacetamido-L-lyxo-hex-1-enitol with daunomycinone in the presence of anhydrous toluene-p-sulfonic acid in benzene, followed by removal of the N- and O-protecting groups under mild con