65827-66-9

Basic information

• Product Name: 1-O-Methyl-3-amino-3-C-methyl-4,6-O-benzyliden-2,3-didesoxy-α-D-arabino-hexopyranose
• Synonyms: 1-O-Methyl-3-amino-3-C-methyl-4,6-O-benzyliden-2,3-didesoxy-α-D-arabino-hexopyranose
• CAS NO: 65827-66-9
• Molecular Weight: 279.336
• Mol File: 65827-66-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-O-Methyl-3-amino-3-C-methyl-4,6-O-benzyliden-2,3-didesoxy-α-D-arabino-hexopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1-O-Methyl-3-amino-3-C-methyl-4,6-O-benzyliden-2,3-didesoxy-α-D-arabino-hexopyranose(65827-66-9)
• EPA Substance Registry System: 1-O-Methyl-3-amino-3-C-methyl-4,6-O-benzyliden-2,3-didesoxy-α-D-arabino-hexopyranose(65827-66-9)

Safety Data

• Hazardous Substances Data: 65827-66-9(Hazardous Substances Data)

Upstream product

• 63803-49-6 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-methylene-α-D-erythro-hexopyranoside 
• 65827-65-8 O^4',O^6'-(R)-benzylidene-O^1'-methyl-spiro[aziridine-2,3'-(α-D-arabino-2,3-dideoxy-hexopyranose)] 

Downstream Products

• 65827-68-1 methyl 3-acetamido-4-O-benzoyl-6-bromo-2,3,6-trideoxy-3-C-methyl-α-D-arabino-hexopyranoside 
• 85687-30-5 methyl 4-O-benzoyl-6-bromo-2,3,6-trideoxy-3-C-methyl-3-(trifluoroacetamido)-α-D-ribo-hexopyranoside 
• 95087-01-7 4-O-benzoyl-2,3,6-trideoxy-3-C-methyl-3-trifluoroacetamido-α-L-lyxo-hexopyranose 
• 95087-00-6 4-O-benzoyl-2,3,6-trideoxy-3-C-methyl-3-trifluoroacetamido-β-L-lyxo-hexopyranose 
• 85687-32-7 methyl 4-O-benzoyl-2,3,6-trideoxy-3-C-methyl-3-(trifluoroacetamido)-α-D-ribo-hexopyranoside 
• 95086-99-0 methyl 4-O-benzoyl-2,3,6-trideoxy-3-C-methyl-3-trifluoroacetamido-β-L-lyxohexopyranoside 
• 95086-98-9 methyl 4-O-benzoyl-2,3,6-trideoxy-3-C-methyl-3-trifluoroacetamido-α-D-erythro-hex-5-enopyranoside 
• 85687-29-2 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-methyl-3-trifluoroacetamido-α-D-ribo-hexopyranoside 
• 65827-67-0 methyl 3-acetamido-4,6-O-benzylidene-2,3-dideoxy-3-C-methyl-α-D-arabino-hexopyranoside 

Relevant articles and documents

Branched-chain Sugars. Part 11. An Approach to the Synthesis of D-Evernitrose via the Addition of Iodine Azide to a C-Methylene Sugar

Methyl 3-acetamido-2,3,6-trideoxy-3-C,4-O-dimethyl-α-D-arabino-hexopyranoside (16), a known precursor of D-evernitrose, has been synthesised via the addition of iodine azide to methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-methylene-α-D-erythro-hexopyranoside