95091-40-0

Upstream product

• 95091-20-6 2-(4-Methoxy-5-methyl-4-phenylsulfanyl-hex-5-enyloxy)-tetrahydro-pyran 
• 33821-94-2 3-(tetrahydro-2H-pyran-2-yloxy)propyl bromide 
• 93233-72-8 (1-Methoxy-2-methyl-allylsulfanyl)-benzene 

Downstream Products

• 95091-28-4 2-((Z)-4-Methoxy-5-methyl-6-phenylsulfanyl-dodec-4-enyloxy)-tetrahydro-pyran 
• 95091-30-8 2-Methoxy-2-((E)-1-methyl-2-phenylsulfanyl-vinyl)-1-phenyl-5-(tetrahydro-pyran-2-yloxy)-pentan-1-ol 
• 95091-31-9 4-Methoxy-4-((E)-1-methyl-2-phenylsulfanyl-vinyl)-1-(tetrahydro-pyran-2-yloxy)-decan-5-ol 
• 95091-14-8 2-[3-(4-Methyl-2-phenyl-furan-3-yl)-propoxy]-tetrahydro-pyran 

Relevant academic research and scientific papers

α-METHOXYALLYL SULFIDES AS A NOVEL HOMOENOLATE DIANION EQUIVALENT

α-Methoxyallyl sulfides 1 proved to serve a novel homoenolate dianion equivalent.Introduction of two electrophiles into 1 was realized by successive regiospecific reaction of an allylic moiety with electrophiles intervented by an acid-catalyzed thioallylic rearrangement.Facile desulfurization of the products under mild conditions afforded a variety of α,β-unsaturated carbonyl compounds and 2,3,4-trisubstituted furans.