595-49-3Relevant articles and documents
PROCESS FOR NITROALKANE RECOVERY BY AQUEOUS PHASE RECYCLE TO NITRATION REACTOR
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Page/Page column 16-17, (2011/05/06)
Disclosed are a process and an apparatus for synthesizing nitroalkanes by reaction of a hydrocarbon feedstock with aqueous nitric acid. Energy and capital costs may be reduced by recycling a majority of the aqueous phase back to the reactor.
Radical-Nucleophilic Substitution (SRN1) Reactions. Part 6. N-Anions of Diazoles in SRN1 and Oxidative Additions
Adebayo, Adelaide T. O. M.,Bowman, W. Russell,Salt, W. G.
, p. 1415 - 1421 (2007/10/02)
The anions of imidazole, benzimidazole, 5(6)-nitrobenzimidazole, and 5(and 6)-nitro-1H- and -2H-indazoles have been shown to undergo oxidative addition to the anion of 2-nitropropane (using potassium ferricyanide and sodium persulphate), and SRN1 reactions with Me2C(X)NO2 (X = Cl, Br, and NO2) to yield the corresponding 1-(1-methyl-1-nitroethyl) derivatives.The anions of 5(6)-nitrobenzimidazole and 5(6)-nitro-1H- and -2H-indazoles underwent reaction with p-nitrobenzyl chloride by a SRN1 and/or SN2 mechanism to yield the corresponding 1-(p-nitrobenzyl) derivatives.The ambident anions of 5- and 6-nitrobenzimidazole, 5-nitro-1H- and -2H-indazoles, and 6-nitro-1H- and -2H-indazoles gave ca. 50:50 mixtures of the N-1 alkylation products resulting from respective pairs of ambident anions.The 1-(1-methyl-1-nitroethyl) derivatives of benzimidazole and 5- and 6-nitro-1H-indazole underwent further substitution of the aliphatic nitro group with the respective diazole to yield 2,2-di(benzimidazol-1-yl)-, 2,2-dipropanes.
SRN1 AND OXIDATIVE ADDITION REACTIONS OF NITROIMIDAZOLE ANIONS
Adebayo, Adelaide T. O. M.,Bowman, Russell,Salt, W. G.
, p. 1943 - 1946 (2007/10/02)
The anions of 2- and 4(5)-nitroimidazoles react with aliphatic substituted nitro compounds and p-nitrobenzyl chloride by a SRN1 mechanism, or by oxidative addition to the anion of 2-nitropropane, to yield 1-alkyl-2-(or 4-)-nitroimidazoles.
