951133-45-2

Upstream product

• 66-25-1 hexanal 
• 951133-73-6 (R)-(1,3-Butadienyl)-p-tolyl-sulfoxid 
• 1092556-95-0 C₂₄H₂₇NO₅S 

Downstream Products

• 951133-52-1 (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triisobutylsilane 
• 951133-53-2 (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]tributylsilane 
• 951133-55-4 (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]trihexylsilane 
• 951133-77-0 (-)-(5S)-(4E)-4-(p-tolylsulfonyl)deca-1,3-dien-5-ol 
• 951133-50-9 (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]t-butyldimethylsilane 
• 951133-79-2 (2R,5S)-5-pentyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-methanol 
• 951133-63-4 (2S,5S)-5-pentyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-methanol 
• 951133-51-0 (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triethylsilane 
• 1092556-97-2 C₂₄H₂₇NO₅S 
• 951133-94-1 (+)-(2S,3S,5R)-3-phenylcarbonyloxy-5-hydroxymethyl-2-pentyl-tetrahydrofuran 
• 128707-15-3 (2R,4S,5S)-tetrahydro-4-hydroxy-5-pentyl-2-furfuraldehyde (benzoate) 
• 951133-93-0 (+)-(2S,3S,5R)-5-(tert-butyldimethylsilyloxymethyl)-3-phenylcarbonyloxy-2-pentyl-tetrahydrofuran 
• 951133-90-7 (-)-(2S,3S,4S,5S)-2-(tert-butyldimethylsilyloxymethyl)-3,4-epoxy-5-pentyl-4-(p-tolylsulfonyl)tetrahydrofuran 
• 951133-75-8 (+)-(1S)-(2E)-[4-(p-tolylsulfonyl)deca-1,3-dien-5-yloxy]tributylsilane 

Relevant academic research and scientific papers

Highly diastereoselective Katsuki-Jacobsen oxidation-epoxidation of α-silyloxy sulfinyl dienes: Synthetic applications

(Chemical Equation Presented) Katsuki-Jacobsen oxidation-epoxidation of acyclic α-silyloxy sulfinyl dienes, followed by acid-promoted cyclization, leads to 2,5-trans-sulfonyl dihydrofurans with good selectivities. As an application, the formal syntheses of (6S,7S,9R,10R)- and (6S,7S,9S,10S)-6,9- epoxynonadec-18-ene-7,10-diols is reported.

Katsuki-Jacobsen oxidation-epoxidation of α-silyloxy sulfinyl dienes: application to the formal synthesis of (6S,7S,9R,10R)-6,9-epoxynonadec-18-ene-7,10-diol

The Katsuki-Jacobsen oxidation-epoxidation of acyclic α-silyloxy sulfinyl dienes, followed by acid-promoted cyclization, leads to 2,5-trans sulfonyl dihydrofurans with good selectivities. As an application, the formal synthesis of (6S,7S,9R,10R)-6,9-epoxy