951386-58-6

Basic information

• Product Name: 1-(2-(allyloxy)ethyl)-2-bromobenzene
• Synonyms: 1-(2-(allyloxy)ethyl)-2-bromobenzene
• CAS NO: 951386-58-6
• Molecular Weight: 241.128
• Mol File: 951386-58-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(2-(allyloxy)ethyl)-2-bromobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-(allyloxy)ethyl)-2-bromobenzene(951386-58-6)
• EPA Substance Registry System: 1-(2-(allyloxy)ethyl)-2-bromobenzene(951386-58-6)

Safety Data

• Hazardous Substances Data: 951386-58-6(Hazardous Substances Data)

Upstream product

• 1074-16-4 2-bromophenylethyl alcohol 
• 106-95-6 allyl bromide 

Downstream Products

• 951386-57-5 2-(2-allyloxyethyl)-phenylboronic acid 
• 1074-16-4 2-bromophenylethyl alcohol 

Relevant articles and documents

Reliably Regioselective Dialkyl Ether Cleavage with Mixed Boron Trihalides

A protocol for the regioselective cleavage of unsymmetrical alkyl ethers to generate alkyl alcohol and alkyl bromide products is described. A mixture of trihaloboranes triggers this conversion and exhibits improved reactivity profiles (regioselectivity and yield) compared with BBr3 alone. Additionally, this procedure allows the efficient synthesis of (B-Cl) dialkyl boronate esters. There are limited methods to generate acyclic dialkoxyboryl chlorides, and these intermediates constitute important synthons in main-group chemistry.