95178-09-9Relevant academic research and scientific papers
Organoselenium-Catalyzed Aza-Wacker Reactions: Efficient Access to Isoquinolinium Imides and an Isoquinoline N -Oxide
Li, Huimin,Liao, Lihao,Zhao, Xiaodan
supporting information, p. 1688 - 1692 (2019/08/26)
An efficient approach for the organoselenium-catalyzed aza-Wacker reaction of olefinic hydrazones and an oxime to form isoquinolinium imides and an isoquinoline N -oxide is developed. This transformation involves a direct intramolecular C-H amination using hydrazones and an oxime as imine-type nitrogen sources. This work not only provides a new approach for the construction of isoquinoline derivatives, but also expands the scope of nitrogen sources in electrophilic selenium catalysis.
The Acylation of 5H-2,3-Benzodiazepines. Reactions of 4-Phenyl-5H-2,3-benzodiazepine with Acyl Chlorides to give N-Acylaminoisoquinolines and/or Acylated Dimers. X-Ray Molecular Structure of 5,14-Diacetyl-4,5,8,9-tetrahydro-2,7-diphenyl-4,8-o-benzeno-3,9-
Motion, Keith R.,Mundo, David P.,Sharp, John T.,Walkinshaw, Malcolm D.
, p. 2027 - 2034 (2007/10/02)
The acylation of 4-phenyl-5H-2,3-benzodiazepine (1) with acyl halides in benzene or toluene takes either or both of two reaction paths depending on the nature of the acylation reagent, the order of mixing, and the reaction temperature.One pathway leads to
