952-28-3

Upstream product

• 49645-23-0 N,N′-[1,1′-biphenyl]-4,4′-diyl-bis-(formamide) 
• 92-87-5 p,p'-diaminobiphenyl 
• 503-38-8 trichloromethyl chloroformate 

Downstream Products

• 99536-59-1 tetrakis(acetonitrile)copper(I) hexafluorophosphate 
• 918414-16-1 [μ-(4,4'-diisocyanobiphenyl)(Au(1-decyloxy-2,3,5,6-tetrafluorobenzene(-1H)))2] 
• 918414-14-9 [μ-(4,4'-diisocyanobiphenyl)(Au(1-hexyloxy-2,3,5,6-tetrafluorobenzene(-1H)))2] 
• 918414-15-0 [μ-(4,4'-diisocyanobiphenyl)(Au(1-octyloxy-2,3,5,6-tetrafluorobenzene(-1H)))2] 
• 918414-13-8 [μ-(4,4'-diisocyanobiphenyl)(Au(1-butoxy-2,3,5,6-tetrafluorobenzene(-1H)))2] 
• 80984-01-6 BrMn(CO)3(CNC₆H₄C₆H₄CN)2 
• 74620-95-4 (Rh(4,4'-diisocyanobiphenyl)2⁽¹⁺⁾*Cl^(1-))n 
• 74620-95-4 (Rh(4,4'-diisocyanobiphenyl)2⁽¹⁺⁾*Cl^(1-))n 

Relevant academic research and scientific papers

Synthesis and antiproliferative activity of aromatic and aliphatic bis[aminomethylidene(bisphosphonic)] acids

A series of aromatic and aliphatic bis[aminomethylidene(bisphosphonic)] acids was synthesized in the reaction of triethylphosphite with isonitriles followed by hydrolysis or dealkylation. The in vitro anti-proliferative effect of all synthesized tetraphosphonic acids against MCF-7 breast cancer cells, J774E macrophages and HL-60 promyelocytic leukemia cells was determined. Three aromatic derivatives (5a, 5f and 5j) showed a similar or higher anti-proliferative activity than zoledronic acid.

A general simple methodology for synthesis of isonitriles using benzene-1,3-disulfonyl dichloride

Isonitrile derivatives have been synthesized in good to high yields by dehydration of aliphatic and aromatic formamides in the presence of benzene-1,3-disulfonyl dichloride as easy and efficient reagent.

Synthesis, characterization and mechanochromic behavior of binuclear gold (I) complexes with various diisocyano bridges

A series of binuclear gold (I) complexes were synthesized. Their structures were characterized by elemental analyses, IR spectrometry, UV-Vis spectroscopy and single crystal X-ray diffraction. Their fluorescent mechanochromic (tribochromic) properties were investigated. The results of the mechanochromic studies suggested that the gold complexes with methylsubstituted phenyl bridges exhibited mechanochromism and a 100 nm red-shift of fluorescent spectrum could be observed after grinding. The complex with a diphenylmethane bridge exhibited mechanochromism with a change in fluorescence from green to blue (25 nm red-shift after grinding). The ground complexes reverted to their original states by treatment with CH2Cl2. No mechanochromism was observed for either the biphenyl or diphenylethane containing complexes.