95210-02-9Relevant academic research and scientific papers
A novel racemization mechanism for the α-hydroxy ketone moiety(C9-position) of optically active anthracyclinone derivatives
Terashima,Tamoto
, p. 2589 - 2592 (1983)
The facile acid-catalyzed racemization of optically active anthracyclinone derivatives((S)(+)-1a,b) was found to proceed through the ring-expanded seven-membered α-hydroxyketones(2 and/or 3 for (S)(+)-1a) by subjecting various plausible intermediates to t
