952296-95-6

Basic information

• Product Name: CpFe(CO)2(κSe-SeCS2Ph)
• Synonyms: CpFe(CO)2(κSe-SeCS2Ph)
• CAS NO: 952296-95-6
• Molecular Weight: 409.171
• Mol File: 952296-95-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: CpFe(CO)2(κSe-SeCS2Ph)(CAS DataBase Reference)
• NIST Chemistry Reference: CpFe(CO)2(κSe-SeCS2Ph)(952296-95-6)
• EPA Substance Registry System: CpFe(CO)2(κSe-SeCS2Ph)(952296-95-6)

Safety Data

• Hazardous Substances Data: 952296-95-6(Hazardous Substances Data)

Upstream product

• 16911-89-0 phenyl chlorodithioformate 

Downstream Products

• 952296-98-9 CpFe(CO)(κ2S,Se-SeCS2Ph) 

Relevant articles and documents

Synthesis and structures of CpFe(CO)2(κE-ECS2Ph) and [CpFe(CO)(κ2S,E-ECS2Ph)] (E = S, Se)

The iron trithiocarbonato complex CpFe(CO)2(κS-SCS2Ph) (1a) and its selenodithiocarbonato analogue CpFe(CO)2(κSe-SeCS2Ph) (1b) were generated by room temperature reactions of (μ-Ex)[CpFe(CO)2]2 (E = S; x = 2, 3. E = Se; x = 1) with PhSC(S)Cl. These compounds can be converted into the complexes CpFe(CO)(κ2S,E-ECS2Ph) [E = S (2a), Se (2b)], in which the trithiocarbonato or the selenodithiocarbonato ligand is bonded to the iron in a chelate form, under photolytic conditions. The composition and structure of all products have been verified by elemental analyses, IR and 1H NMR spectroscopies. The crystal structures for compounds 1a, 1b, and 2b show a three-legged piano-stool configuration at Fe in each complex. The spectroscopic and structural data in this work are commensurate with the electronic factor of the S- and Se-donor ligands.