95235-30-6

Basic information

• Product Name: 4-Hydroxy-4'-isopropoxydiphenylsulfone
• Synonyms: BPS-monoP;WinCon-8 (4-Hydroxy-4'-Isopropoxydiphenylsulfon;4-Hydroxy-4'-isoprop;4-hydroxy-4-Isopropoxydiphenylsulfone (D-8);Anti-UBE1L, C-Terminal antibody produced in rabbit;Ubiquitin-activating enzyme 7;Ubiquitin-activating enzyme E1 homolog;ANTI-UBA7(N-TERMINAL) antibody produced in rabbit
• CAS NO: 95235-30-6
• Molecular Formula: C15H16O4S
• Molecular Weight: 292.35
• EINECS: 405-520-5
• Mol File: 95235-30-6.mol
• Article Data: 11

Chemical Properties

• Melting Point: 129 °C
• Boiling Point: 478.789 °C at 760 mmHg
• Flash Point: 243.363 °C
• Appearance: /
• Density: 1.251 g/cm³
• Vapor Pressure: 0Pa at 27℃
• Storage Temp.: -20°C
• Solubility: 0.891 in mg/100g standard fat at 20 ℃
• PKA: 7.24±0.15(Predicted)
• Water Solubility: 19.7mg/L at 25℃
• CAS DataBase Reference: 4-Hydroxy-4'-isopropoxydiphenylsulfone(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Hydroxy-4'-isopropoxydiphenylsulfone(95235-30-6)
• EPA Substance Registry System: 4-Hydroxy-4'-isopropoxydiphenylsulfone(95235-30-6)

Safety Data

• Hazard Codes: N
• Statements: 51/53
• Safety Statements: 61
• Hazardous Substances Data: 95235-30-6(Hazardous Substances Data)

Usage

Description

4-Hydroxy-4'-isopropoxydiphenylsulfone is an organic compound characterized by its unique molecular structure, featuring a sulfonyl bridge connecting two phenyl rings, one of which has a hydroxyl group and the other an isopropoxy substituent. 4-Hydroxy-4'-isopropoxydiphenylsulfone exhibits specific chemical and physical properties that make it suitable for various applications.

Uses

Used in Color Developing Dyes:
4-Hydroxy-4'-isopropoxydiphenylsulfone is used as a color developing dye for its ability to participate in dye synthesis processes. It can be utilized in the development of various types of dyes, including fluoran, phthalide, lactam, triphenylmethane, spiropyran, and other leuco dyes. Its versatility allows it to be mixed in different combinations with other dyes to achieve desired color outcomes in various applications.

Flammability and Explosibility

Notclassified

Synthesis

30.3 g of bis(p-hydroxyphenyl)sulfone, 18.5 g of isopropylbromide, and 22.2 g of potassium carbonate as acid-binding agent were added to 200 ml of dimethylformamide, then stirred for 4 hours at about 120° C. and dimethylformamide was distilled off under reduced pressure. When this was accomplished, chloroform was added to the residue to extract crude 4-hydroxy-4'-isopropoxydiphenylsulfone. Then this crude compound was refined by using a silica gel column chromatography and 15.7 g of 4-hydroxy-4'-isopropoxydiphenylsulfone was obtained in white microfine crystals with a melting point of 129.0°~131.0° C.

Upstream product

• 116763-20-3 4,4'-diisopropoxydiphenylsulfone 
• 75-30-9 2-iodo-propane 
• 80-09-1 4,4'-sulfonediphenol 
• 75-26-3 isopropyl bromide 

Relevant articles and documents

Nickel Hydride Catalyzed Cleavage of Allyl Ethers Induced by Isomerization

This report discloses the deallylation of O - and N -allyl functional groups by using a combination of a Ni-H precatalyst and excess Bronsted acid. Key steps are the isomerization of the O - or N -allyl group through Ni-catalyzed double-bond migration followed by Bronsted acid induced O/N-C bond hydrolysis. A variety of functional groups are tolerated in this protocol, highlighting its synthetic value.

COLOR DEVELOPING COMPOSITION CONTAINING MOLECULAR COMPOUND, AND RECORDING MATERIAL

Provided is a color-developing composition containing a molecular compound which has as a component compound a compound represented by formula (I) [wherein Y represents a C1-C12 hydrocarbon group which is chained or branched and saturated or unsaturated, or a C1-C8 hydrocarbon group which is chained or branched, saturated or unsaturated and has an ether or thioether bond; R1, R2, R3 and R4 each independently represent a C1-C6 alkyl group or C2-C6 alkenyl group; n, p, q and r each represents any integer of 0 to 4; and m represents any integer of 0 to 2]. Also provided is a recording material with a sufficient color-forming sensitivity, superior storage stability, and especially with an extremely little background fogging in a heat resistance test.

Industrial process for the production of diphenyl sulfone compounds

A process for producing 4-isopropoxy-4′-hydroxydiphenyl sulfone useful as the developer for leuco dyes to be used in thermosensible papers, which is excellent in productivity, economical efficiency and safety and permits the production of the compounds from constantly available raw materials. This process is improved in productivity and economical efficiency as compared with those of the prior art both by shortening the production time by the use of an isopropyl iodide, which is more reactive than isopropyl bromide which have been used in the prior art.