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[Rh(duroquinone)(azulene)](PF6) is a complex organic-inorganic hybrid compound, featuring a rhodium (Rh) metal center coordinated with duroquinone and azulene ligands. Duroquenone is a redox-active ligand, while azulene is a polycyclic aromatic hydrocarbon. The compound is typically represented with a hexafluorophosphate (PF6) counterion, which balances the overall charge of the complex. [Rh(duroquinone)(azulene)](PF6) is of interest in the field of coordination chemistry and organometallic chemistry, potentially for its electronic properties and applications in catalysis or materials science.

95248-03-6

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95248-03-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 95248-03-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,5,2,4 and 8 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 95248-03:
(7*9)+(6*5)+(5*2)+(4*4)+(3*8)+(2*0)+(1*3)=146
146 % 10 = 6
So 95248-03-6 is a valid CAS Registry Number.

95248-03-6Downstream Products

95248-03-6Relevant academic research and scientific papers

AZULENE AS A LIGAND IN CATIONIC RHODIUM AND IRIDIUM COMPLEXES. CRYSTAL STRUCTURE OF PF6

Oro, L.A.,Valderrama, M.,Cifuentes, P.,Foces-Foces, C.,Cano, F.H.

, p. 67 - 78 (1984)

Rhodium or iridium complexes of formula + have been prepared by treating 2 complexes with silver salts and azulene, and also by treating + with azulene.The reactions of some representative complexes have been studied.Reaction of 2+ with azulene appears to give dinuclear diazulene cationic complexes.The crystal structure of compound PF6 has been solved by X-ray methods.It crystallizes in the space group P21/c with cell constants 8.4241(4), 16.6911(8), 15.0026(7) Angstroem, 95.897(6) deg.Refinement gave R=0.027 and Rw=0.032 for 2991 observed reflexions.The Rh atom is coordinated to the five-membered ring, with Rh-C distances shortest for the atoms which are trans to the diolefinic double bonds.The bonding scheme within the azulene ligand differs from that in the parent hydrocarbon.

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