952717-64-5

Upstream product

• 929097-32-5 5-tert-butoxy-7-(tert-butyl-dimethyl-silanyloxy)-4-methyl-3-(trimethyl-silanyloxy)-bicyclo[2.2.2]octan-2-one 
• 929097-27-8 5-tert-butoxy-7-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-4-methyl-bicyclo[2.2.2]octan-2-one 

Relevant academic research and scientific papers

Baeyer-Villiger oxidation of the bicyclo[2.2.2]octanone system revisited: Searching for a modular construction of heavily substituted cyclohexanes based on m-CPBA mediated selective oxygen insertion

Described herein is the use of Baeyer-Villiger oxidation for the selective insertion of oxygen into a variously substituted bicyclo[2.2.2]octanone system, synthesized by a consecutive domino process. By using the appropriate sequence of steps and starting