95274-97-8Relevant academic research and scientific papers
Metal-free desilylative C-C bond formation by visible-light photoredox catalysis
Uygur, Mustafa,Danelzik, Tobias,García Manche?o, Olga
supporting information, p. 2980 - 2983 (2019/03/26)
A newly developed methodology for the use of organosilanes as radical precursors under metal-free and visible-light conditions is presented. The strong oxidant character of the 9-mesityl-10-methylacridinium salt in its excited state enables the transforma
Bis(phenylsulfonyl)methane mediated synthesis of olefins: Via a halogen elimination and double bond migration
Hu, Yanwei,Jiang, Jing,Hu, Ying,Cai, Xin,Wang, Liudi,Chen, Shaohua,Zhang, Shilei,Zhang, Yinan
, p. 2619 - 2622 (2018/04/27)
An effective dehydrochlorination of bis(phenylsulfonyl)alkane to prepare alkene building blocks is developed. The elimination together with double bond migration results in a variety of β,γ-unsaturated bis(phenylsulfonyl)olefins in good yields with only E geometry. The following chemical diversification represents an easy and straightforward access to a series of alkene building blocks.
Reductive cleavage of sulfones and sulfonamides by a neutral organic super-electron-donor (S.E.D.) reagent
Schoenebeck, Franziska,Murphy, John A.,Zhou, Sheng-Ze,Uenoyama, Yoshitaka,Miclo, Yves,Tuttle, Tell
, p. 13368 - 13369 (2008/04/04)
Sulfones and sulfonamides are reductively cleaved using the neutral and easily prepared organic electron-donor, bis-imidazolylidene 3. Copyright
1,3-BENZODITHIOLE TETRAOXIDE AS A CH2(2-) SYNTHON
Kuendig, E. Peter,Cunningham, Allan F.
, p. 6855 - 6860 (2007/10/02)
1,3-Benzodithiole tetraoxide (BDT) 4 is more reactive in alkylation reactions than the commonly used bis(benzenesulfonyl)methane (1).This is demonstrated notably in dialkylations with sterically demanding alkyl halides.Besides its ready access and larger
