953-32-2Relevant academic research and scientific papers
Reactions of Aromatic Diazonium Salts with Esters of Acrylic and Methacrylic Acids in the Presence of O,O′-Diethyl Phosphodithioates
Grishchuk,Gorbovoi,Kudrik,Ganushchak,Kaspruk
, p. 362 - 364 (2007/10/03)
Alkyl 2-(diethoxythiophosphorylthio)-2-phenylpropionates were prepared by reaction of aromatic diazonium salts with esters of acrylic and methacrylic acids in the presence of potassium O,O′-diethyl dithiophosphate in a water-acetone (1 : 2) medium. The reaction is accompanied by formation of aryl O,O′-diethyl phosphodithioates. The diethoxythiophosphorylthioarylation of acrylates readily occurs in the absence of copper salts, thus providing an example of a noncatalytic reaction of diazonium salts with unsaturated compounds in the presence of foreign nucleophiles.
