95345-98-5

Upstream product

• 58298-10-5 [Re2Cl4(μ-bis(diphenylphosphino)methane)2] 
• 17084-13-8 potassium hexafluorophosphate 
• 75-05-8 acetonitrile 
• 60969-19-9 thallium(I) hexafluorophosphate 

Downstream Products

• 97391-38-3 Re₂⁽⁵⁺⁾*3Cl^(1-)*2CH₂(P(C₆H₅)2)2*2CH₃CN*2PF₆^(1-)={Re₂Cl₃(CH₂(P(C₆H₅)2)2)2(CH₃CN)2}(PF₆)2 
• 95345-99-6 Re₂Cl₃(((C₆H₅)2P)2CH₂)2(NCCH₃)2⁽¹⁺⁾*Cl^(1-)=Re₂Cl₃(((C₆H₅)2P)2CH₂)2(NCCH₃)2Cl 

Relevant academic research and scientific papers

Unusual reactivity associated with the triply bonded Re24+ core: Facile reaction of Re2Cl4(Ph2PCH2PPh2) 2 with nitriles to afford the cations [Re2Cl3

The triply bonded complex Re2Cl4(dppm)2 (dppm = Ph2PCH2PPh2) reacts with nitriles (RCN) to form complexes of stoichiometry [Re2Cl3(dppm)2(NCR)2]X