95361-46-9Relevant academic research and scientific papers
MgBr2-PROMOTED ELECTROSYNTHESIS OF SULFENIMINES (THIOOXIMES) FROM α-AMINO-ALKANOATES AND DIARYL/DIALKYL DISULFIDES IN A CH2Cl2-H2O TWO-PHASE SYSTEM. A STRAIGHTFORWARD PREPARATION OF C(6)/C(7)-SULFENIMINE DERIVATIVES OF PENICILLIN AND CEPHALOSPORIN
Torii, Sigeru,Tanaka, Hideo,Hamano, Sin-ichi,Tada, Nobuhito,Nokami, Junzo,Sasaoka, Michio
, p. 1823 - 1826 (2007/10/02)
Direct transformation of α-aminoalkanoates and diaryl or dialkyl disulfides to the corresponding sulfenimines by electrolysis in a CH2Cl2-H2O-MgBr2-(Pt electrodes) system and its application to the sulfenylation of C(6)/C(7)-amino groups of penicillin and cephalosporin are described.
