953786-86-2Relevant academic research and scientific papers
Asymmetric intermodular heck-type reaction of acyclic alkenes via oxidative palladium(II) catalysis
Yoo, Kyung Soo,Park, Chan Pil,Yoon, Cheol Hwan,Sakaguchi, Satoshi,O'Neill, Justin,Jung, Kyung Woon
, p. 3933 - 3935 (2007)
Herein, we report an asymmetric intermolecular Heck-type reaction of acyclic alkenes by using a palladium-pyridinyl oxazoline diacetate complex under oxidative palladium(II) catalysis conditions. A premade palladium-ligand complex afforded higher enantioselectivities than a corresponding premixed palladium-ligand system, while offering enhanced asymmetric induction when compared to known intermolecular Heck-type protocols.
