95383-62-3Relevant academic research and scientific papers
OXIDATIVE KUPPLUNG VON 1,2-DIENEN MIT ISOCYANATEN AM LIG-NICKEL(0)-SYSTEM
Hoberg, Heinz,Suemmermann, Klaus
, p. 239 - 248 (1984)
Isocyanates undergo a 1/1 oxidative coupling reaction with 1,2-dienes and Lig-Ni0 systems to give azanickelacyclopentanones.The coupling to form the nickela complexes proceeds in such a way that the exo-methylene group is conjugated with the carbonyl group.The influence of the ligands and the temperature on the regioselectivity of the C-C coupling is reported.
