Journal of Organometallic Chemistry p. 239 - 248 (1984)
Update date:2022-08-05
Topics:
Hoberg, Heinz
Suemmermann, Klaus
Isocyanates undergo a 1/1 oxidative coupling reaction with 1,2-dienes and Lig-Ni0 systems to give azanickelacyclopentanones.The coupling to form the nickela complexes proceeds in such a way that the exo-methylene group is conjugated with the carbonyl group.The influence of the ligands and the temperature on the regioselectivity of the C-C coupling is reported.
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