95469-17-3Relevant academic research and scientific papers
N-deuterium methylamine compound and preparation method thereof
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Paragraph 0057-0059, (2020/07/12)
The invnetion discloses an N-deuterium methylamine compound and a preparation method thereof. The preparation method comprises the following steps: mixing an amine compound, a deuterium source and a photocatalyst, and carrying out a reaction in an inert g
Picosecond Dynamics of Proton Transfers
Manring, Lewis E.,Peters, Kevin S.
, p. 6452 - 6458 (2007/10/02)
The dynamics of proton transfer within an acid-base pair, which is created by a photoinduced electron transfer from an amine to a ketone, is investigated through picosecond absorption spectroscopy.Questions relating to molecular motion within the encounter complex and the distance dependence of proton transfer are addressed.Specifically, for substituted benzophenones and diphenylmethylamine, isotope and solvent dependence studies reveal that, although an acid-base pair is formed as an encounter complex, prior reorientation within the complex must take place before proton transfer.Other systems investigated include the transfer of a proton from the radical cation of N-methylacridan to the radical anions of benzophenone and anthraquinone as well as an intramolecular proton transfer for a molecule containing dimethylaniline linked to benzophenone by a methylene bridge.
