95480-84-5

Usage

InChI:InChI=1/C26H42O2/c1-18(2)6-5-7-19(3)24-14-12-22-11-9-20(17-26(22,24)4)8-10-21-16-23(27)13-15-25(21)28/h8,10,18-19,22-24,27H,5-7,9,11-17H2,1-4H3/b20-8+,21-10-/t19-,22-,23+,24-,26+/m1/s1

Upstream product

• 67-97-0 vitamin D₃ 
• 67-97-0 5,6-trans-vitamin D₃ 
• 155589-97-2 (5E)-10-Oxo-19-norcholecalciferolacetat 
• 13482-22-9 4-hydroxycyclohexanone 
• 2871-23-0 (5Z,7E)-3β-acetoxy-9,10-secocholesta-5,7,10(19)-triene 
• 149981-53-3 (5Z)-10-Oxo-19-norcholecalciferolacetat 

Downstream Products

• 67-97-0 5,6-trans-vitamin D₃ 

Relevant academic research and scientific papers

A Selective Degradation of the Exomethylene Group of Vitamin D. - A Simple Entry to 10-Oxo-19-norcholecalciferol and 10-Oxo-19-norergocalciferol

Nitrile oxides, generated in situ from nitroalkanes, add exclusively to the exomethylene group of (Z)- and (E)-vitamin D3 acetates (1a, 12a) and D2 acetates (1b, 12b).The so generated spirocyclic isoxazoline derivatives are transform

Biomimetic oxidation of vitamin D by iron-sulfur model cluster and dioxygen system

Oxidation of vitamin D3 with a combination of iron-sulfur protein model cluster, (n-Bu4N)2[Fe4S4(SPh)4], and molecular oxygen produced (5E)-10-oxo-10-norvitamin D3 and 8α-hydroxy-9,10-seco-4,6,10(19)-cholestatrien-3-one, a new type of vitamin D metabolites, mimicking biological oxidation.