955024-69-8Relevant articles and documents
Gold-catalyzed cyclization of (ortho-alkynylphenylthio)silanes: Intramolecular capture of the vinyl-au intermediate by the silicon electrophile
Nakamura, Itaru,Sato, Takuma,Terada, Masahiro,Yamamoto, Yoshinori
, p. 4081 - 4083 (2007)
The gold-catalyzed cyclization of (ortho-alkynylphenylthio)silanes 1 produced the corresponding 3-silylbenzo[b]thiophenes 2 in good to excellent yields. For example, the reaction of [2-(1-pentynyl)phenylthio] triisopropylsilane 1a, [2-(p-anisylethynyl)phe