95526-71-9Relevant academic research and scientific papers
Radical-induced 1,3-Rearrangemets of Allylic Sulfones bearing an Alkylthio or Arylthio Substituent at the α-Position
Fox, Judith M.,Morris, Clare M.,Smyth, G. Darren,Whitman, Gordon H.
, p. 731 - 738 (2007/10/02)
1-Methylthio-1-p-tolylsulfonylprop-2-ene 2 underwent 1,3-rearrangement under conditions of radical initiation with migration of the p-tolylsulfonyl group by a process considered to have involved addition-elimination of arylsulfonyl radicals.In contrast, t
"Syn-Effect" in the Conversion of (E)-Vinylic Sulfones to the Corresponding Allylic Sulfones
Hirata, Takaki,Sasada, Yoshihiro,Ohtani, Takashi,Asada, Takahiro,Kinoshita, Hideki,et al.
, p. 75 - 96 (2007/10/02)
It was found that (E)-vinylic sulfones preferentially afford (Z)-allylic sulfones as kinetically-controlled products by treatment with a base under mild conditions, while (Z)-vinylic sulfones give (E)-allylic sulfones.Such stereochemical relationship was
