955361-18-9Relevant academic research and scientific papers
Hydrogen-bond-promoted palladium catalysis: Allylic alkylation of indoles with unsymmetrical 1,3-disubstituted allyl acetates using chiral bis(sulfoxide) phosphine ligands
Du, Le,Cao, Peng,Xing, Junwei,Lou, Yazhou,Jiang, Liyin,Li, Liangchun,Liao, Jian
supporting information, p. 4207 - 4211 (2013/05/09)
A DYKAT die hard: A new class of chiral BiSO-P ligands were effective for an unprecedented palladium-catalyzed asymmetric allylic alkylation of indoles with the racemic title acetates through a dynamic kinetic asymmetric transformation (DYKAT). The hydrogen bond formed between the sulfinyl group of the ligand and NH of indole plays an important role in the reaction. Copyright
