95548-89-3Relevant academic research and scientific papers
Metal- catalysed Addition of β-Dicarbonyl Compounds to the Nitrile Carbon of Benzoyl Cyanide. Synthesis of 1-Amino-1-benzoyl-2,2-diacylethenes
Basato, Marino,Corain, Benedetto,Cofler, Marino,Veronese, Augusto C.,Zanotti, Guiseppe
, p. 1593 - 1594 (1984)
The complex (Hacac=pentane-2,4-dione) selectively catalyses addition of the intercarbonylic carbon atom of β-diketones to the cyano group of benzoyl cyanide, whereas usual basic organic catalysts lead to attack on the carbonyl carbon atom with
Reactions of β-Dicarbonyl Compounds with Acyl Cyanides Catalyzed or Promoted by Metal Centres in the Homogeneous Phase
Veronese, Augusto C.,Callegari, Rosella,Basato, Marino,Valle, Giovanni
, p. 1779 - 1786 (2007/10/02)
The C-C bond-forming reaction between β-dicarbonyl compouds and acyl cyanides is catalyzed by nickel acetylacetonate or promoted by tin tetrachloride.Thus, β-diketones react with acyl cyanides in the presence of catalytic amounts of to give β-
